Analytical Methods in Photoelectrochemical Treatment of Phenol

dc.contributor.authorLopes, Paulo R. M. [UNESP]
dc.contributor.authorMontagnolli, Renato N. [UNESP]
dc.contributor.authorBidoia, Ederio Dino [UNESP]
dc.contributor.institutionUniversidade Estadual Paulista (Unesp)
dc.date.accessioned2013-09-30T18:47:18Z
dc.date.accessioned2014-05-20T13:56:19Z
dc.date.available2013-09-30T18:47:18Z
dc.date.available2014-05-20T13:56:19Z
dc.date.issued2011-09-01
dc.description.abstractThe aim of the study was to propose a treatment of simulated wastewater containing phenol by photocatalytic and photolytic processes and analyze the toxicity of these phenolic solutions. Two treatment systems were performed with UV radiation, solid electrodes and electric potential. In the first system (S1) phenol concentration was determined by UV direct spectrophotometry (269 nm) and in the second (S2) by direct photometric method (4-aminoantipyrine). Toxicological tests were carried out using two microorganisms: Escherichia coli and Saccharomyces cerevisiae. S1 results showed that erroneous conclusions can be drawn by absorbance values increase at phenol peak. Nevertheless, direct photometric method was able to identify phenol reduction in S2 and the proposed treatments degraded phenol in solution. Also, in treatment using high energy ultraviolet radiation (UVC), the phenol degradation was mainly due to the photolytic process.en
dc.description.affiliationUniv Estadual Paulista, Dept Bioquim & Microbiol, Inst Biociencias, Rio Claro, SP, Brazil
dc.description.affiliationUnespUniv Estadual Paulista, Dept Bioquim & Microbiol, Inst Biociencias, Rio Claro, SP, Brazil
dc.description.sponsorshipCoordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)
dc.description.sponsorshipConselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)
dc.description.sponsorshipFundação para o Desenvolvimento da UNESP (FUNDUNESP)
dc.description.sponsorshipFundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)
dc.description.sponsorshipIdUNESP/Rio Claro: PRH-05
dc.format.extent1758-1764
dc.identifierhttp://dx.doi.org/10.1590/S0103-50532011000900019
dc.identifier.citationJournal of The Brazilian Chemical Society. São Paulo: Soc Brasileira Quimica, v. 22, n. 9, p. 1758-1764, 2011.
dc.identifier.doi10.1590/S0103-50532011000900019
dc.identifier.fileS0103-50532011000900019.pdf
dc.identifier.issn0103-5053
dc.identifier.lattes9220348583560043
dc.identifier.orcid0000-0001-7040-1983
dc.identifier.scieloS0103-50532011000900019
dc.identifier.urihttp://hdl.handle.net/11449/20131
dc.identifier.wosWOS:000295800700019
dc.language.isoeng
dc.publisherSoc Brasileira Quimica
dc.relation.ispartofJournal of the Brazilian Chemical Society
dc.relation.ispartofjcr1.444
dc.relation.ispartofsjr0,357
dc.rights.accessRightsAcesso aberto
dc.sourceWeb of Science
dc.subjectphenolen
dc.subjectphotocatalysisen
dc.subjectphotolysisen
dc.subjectTiO(2)en
dc.subjecttoxicityen
dc.titleAnalytical Methods in Photoelectrochemical Treatment of Phenolen
dc.typeArtigo
dcterms.rightsHolderSoc Brasileira Quimica
unesp.author.lattes9220348583560043
unesp.author.orcid0000-0003-4886-5292[1]
unesp.author.orcid0000-0003-3801-9631[2]
unesp.author.orcid0000-0001-7040-1983[3]
unesp.campusUniversidade Estadual Paulista (Unesp), Instituto de Biociências, Rio Claropt

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