PHENYLBUTANOID AND TAXANE-LIKE METABOLITES FROM NEEDLES OF TAXUS-BREVIFOLIA

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dc.contributor.authorChu, A.
dc.contributor.authorFurlan, Maysa [UNESP]
dc.contributor.authorDavin, L. B.
dc.contributor.authorZajicek, J.
dc.contributor.authorTowers, GHN
dc.contributor.authorSoucybreau, C. M.
dc.contributor.authorRettig, S. J.
dc.contributor.authorCroteau, R.
dc.contributor.authorLewis, N. G.
dc.contributor.institutionWASHINGTON STATE UNIV
dc.contributor.institutionUNIV BRITISH COLUMBIA
dc.contributor.institutionUniversidade Estadual Paulista (Unesp)
dc.date.accessioned2014-05-20T15:23:48Z
dc.date.available2014-05-20T15:23:48Z
dc.date.issued1994-07-01
dc.description.abstractThe structures for brevifoliol and three baccatin VI derivatives were revised to possess the novel 11(15 --> 1)-abeotaxane tricylic skeleton based on X-ray crystallographic studies. Four more new rearranged taxane derivatives related to brevifoliol and the unusual phenylbutanoid, (-)-rhododendrol, were isolated from the needles of Taxus breuifolia. Their structures were established as 10 beta-benzoxy-5 alpha-(3'-dimethylamino-3'-phenyl)-propanoxy-1 beta-hydroxy- 7 beta,9 alpha,13 alpha-triacetoxy-11(15 --> 1)-abeotaxa-4(20),11-diene; 10 beta-benzoxy-1 beta-hydroxy-5 alpha-(3'-methylamino-3'-phenyl)- propanoxy-7 beta,9 alpha,l3 alpha-triacetoxy-11(15 --> 1)-abeotaxa-4(20),11-diene; 10 beta-benzoxy-5 alpha-cinnamoxy-1 beta-hydroxy-7 beta,9 alpha,13 alpha-triacetoxy-1 1(15 --> 1)-abeotaxa-4(20),11-diene; 10 beta-benzoxy-1 beta,5 alpha-dihydroxy-7 beta,9 alpha,13 alpha-triacetoxy-11(15 --> 1)-abeotaxa-4(20),11-diene and 2(R)-hydroxy-4-(4'-hydroxyphenyl)-butane.en
dc.description.affiliationWASHINGTON STATE UNIV,INST BIOL CHEM,PULLMAN,WA 99164
dc.description.affiliationWASHINGTON STATE UNIV,NMR SPECT CTR,PULLMAN,WA 99164
dc.description.affiliationUNIV BRITISH COLUMBIA,DEPT BOT,VANCOUVER V6T 2Z1,BC,CANADA
dc.description.affiliationUNIV BRITISH COLUMBIA,DEPT CHEM,VANCOUVER V6T 2Z1,BC,CANADA
dc.description.affiliationUNIV ESTADUAL PAULISTA,INST QUIM,BR-14800900 ARARAQUARA,SP,BRAZIL
dc.description.affiliationUnespUNIV ESTADUAL PAULISTA,INST QUIM,BR-14800900 ARARAQUARA,SP,BRAZIL
dc.format.extent975-985
dc.identifierhttp://dx.doi.org/10.1016/S0031-9422(00)90475-8
dc.identifier.citationPhytochemistry. Oxford: Pergamon-Elsevier B.V., v. 36, n. 4, p. 975-985, 1994.
dc.identifier.doi10.1016/S0031-9422(00)90475-8
dc.identifier.issn0031-9422
dc.identifier.lattes1308042794786872
dc.identifier.urihttp://hdl.handle.net/11449/34506
dc.identifier.wosWOS:A1994NY14400032
dc.language.isoeng
dc.publisherElsevier B.V.
dc.relation.ispartofPhytochemistry
dc.relation.ispartofjcr3.186
dc.relation.ispartofsjr1,048
dc.rights.accessRightsAcesso restrito
dc.sourceWeb of Science
dc.subjectTAXUS BREVIFOLIApt
dc.subjectTAXACEAEpt
dc.subjectYEWpt
dc.subjectNEEDLESpt
dc.subjectCRYSTAL STRUCTUREpt
dc.subjectTAXOLpt
dc.subjectDITERPENOIDSpt
dc.subjectTAXANESpt
dc.subject11(15 -]1)-ABEOTAXANESpt
dc.subjectBREVIFOLIOLpt
dc.subjectBACCATIN VIpt
dc.subject10-DEACETYL BACCATIN IIIpt
dc.subjectWINTERSTEIN ESTERpt
dc.subjectPHENYLBUTANOIDSpt
dc.subject(-)-RHODODENDROLpt
dc.titlePHENYLBUTANOID AND TAXANE-LIKE METABOLITES FROM NEEDLES OF TAXUS-BREVIFOLIAen
dc.typeArtigo
dcterms.licensehttp://www.elsevier.com/about/open-access/open-access-policies/article-posting-policy
dcterms.rightsHolderElsevier B.V.
unesp.author.lattes1308042794786872
unesp.campusUniversidade Estadual Paulista (Unesp), Instituto de Química, Araraquarapt

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Artigos - Química Orgânica - IQ