Synthesis and comparison of the activities of a catalyst supported on two silicate materials
dc.contributor.author | Vieira, Eduardo G. [UNESP] | |
dc.contributor.author | Silva, Rafael O. [UNESP] | |
dc.contributor.author | do Carmo, Devaney R. [UNESP] | |
dc.contributor.author | Junior, Enes F. [UNESP] | |
dc.contributor.author | Dias Filho, Newton L. [UNESP] | |
dc.contributor.institution | Universidade Estadual Paulista (Unesp) | |
dc.contributor.institution | Universidade do Extremo Sul Catarinense | |
dc.date.accessioned | 2018-12-11T17:10:03Z | |
dc.date.available | 2018-12-11T17:10:03Z | |
dc.date.issued | 2017-04-15 | |
dc.description.abstract | The focus of this work is inspecting the synthesis and comparison of the activities of a catalyst supported on two silicate materials in the epoxidation of 1-octene. The two new catalyst materials were characterized by infrared spectroscopy, elemental analysis, solid-state 29Si and 13C nuclear magnetic resonance, scanning electronic microscope (SEM) and analysis of nitrogen. Lastly, the two new catalysts, Silsesq-TCA-[(W(CO)3I2)3] and Silica-TCA-[W(CO)3I2] were tested as catalysts in reactions of epoxidation of 1-octene and compared with their analogue not supported [W(CO)3I2(thiocarbamide)]. After an extensive literature search, we verified that our work is the first that has reported the immobilization process of [W(CO)3I2(NCCH3)2] on silsesquioxane and silica gel functionalized with propyl-thiocarbamide groups and their applications as catalysts of reactions of catalytic epoxidation of 1-octene. | en |
dc.description.affiliation | Departamento de Física e Química Unesp-Univ Estadual Paulista, Av. Brasil, 56-Centro, Caixa Postal 31 | |
dc.description.affiliation | Universidade do Extremo Sul Catarinense, Av. Universitaria, 1105, CP 3167 | |
dc.description.affiliation | Departamento de Fitotecnia Tecnologia de Alimentos e Sócio Economia Faculdade de Engenharia de Ilha Solteira Universidade Estadual Paulista | |
dc.description.affiliationUnesp | Departamento de Física e Química Unesp-Univ Estadual Paulista, Av. Brasil, 56-Centro, Caixa Postal 31 | |
dc.description.affiliationUnesp | Departamento de Fitotecnia Tecnologia de Alimentos e Sócio Economia Faculdade de Engenharia de Ilha Solteira Universidade Estadual Paulista | |
dc.format.extent | 197-205 | |
dc.identifier | http://dx.doi.org/10.1016/j.matchemphys.2017.01.045 | |
dc.identifier.citation | Materials Chemistry and Physics, v. 191, p. 197-205. | |
dc.identifier.doi | 10.1016/j.matchemphys.2017.01.045 | |
dc.identifier.file | 2-s2.0-85013391764.pdf | |
dc.identifier.issn | 0254-0584 | |
dc.identifier.scopus | 2-s2.0-85013391764 | |
dc.identifier.uri | http://hdl.handle.net/11449/174255 | |
dc.language.iso | eng | |
dc.relation.ispartof | Materials Chemistry and Physics | |
dc.relation.ispartofsjr | 0,615 | |
dc.rights.accessRights | Acesso aberto | |
dc.source | Scopus | |
dc.subject | 1-Octene | |
dc.subject | Catalysts | |
dc.subject | Heterogeneous catalysts | |
dc.subject | Organometallic complex | |
dc.title | Synthesis and comparison of the activities of a catalyst supported on two silicate materials | en |
dc.type | Artigo | |
unesp.department | Fitotecnia, Tecnologia de Alimentos e Socioeconomia - FEIS | pt |
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