Assessment of an eco-efficient process for the optimization of metal recovery in lithium cobalt oxide and lithium nickel manganese cobalt oxide batteries

Abstract

The expansion of technology motivates the increase of global demands for critical minerals. In this context, the exploration of secondary sources of these components is expanding. End-of-life batteries can be seen as potential sources of lithium, cobalt, nickel and manganese for electric vehicles or diverse applications in electronic equipments. This paper provides a comprehensive evaluation of the recovery of metals from waste batteries with diverse chemistry composition. Lithium cobalt oxide (LCO) and lithium nickel cobalt manganese oxide (NMC) batteries were co-treated with polyvinyl chloride (PVC) channels under supercritical water, varying reaction temperature (400–600 °C) and PVC/Battery composition (0–3 m/m) in a tubular continuous reactor. Results show high recovery rates for all metals, with up to 90% percentage recovery of lithium and cobalt in all cases. Temperature and feed composition were identified as determining factors for the recovery of lithium from LCO batteries. In the case of cobalt, temperature was identified as the most important factor that affects its recovery. The selected optimal conditions for cobalt recovery in the solid products of reactions were identified for batteries LCO and NMC: temperature of 600 °C and PVC/Battery ratio of 3.0 and temperature of 500 °C and PVC/Battery ratio of 1.5, respectively. Environmental impacts, primarily Global Warming Potential (GWP), were minimal, with 4.71·10−5 kg CO2 eq., indicating the benefits of the process as an eco-efficient and promising route for the recycling of valuable metals.