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The crystal field strength parameter and the maximum splitting of the 7F1 manifold of the Eu3+ ion in oxides

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Elsevier B.V.

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Article

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Abstract

We examine, from both the experimental and theoretical point of view, the behavior of the maximum splitting ΔE, of the 7F1 manifold of the Eu3+ ion as a function of the so-called crystal field strength parameter, Nv, in a series of oxides. In connection with the original theory that describes the relation between ΔE and Nv, a more consistent procedure to describe this relation is presented for the cases of small total angular momentum J. Good agreement is found between theory and experiment. © 1995.

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Crystal field splitting, Oxides

Language

English

Citation

Journal of Alloys and Compounds, v. 228, n. 1, p. 41-44, 1995.

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Instituto de Química
IQAR
Campus: Araraquara


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