A new method for the selective quantitation of cyanogenic glycosides by membrane introduction mass spectrometry
| dc.contributor.author | Moraes, LAB | |
| dc.contributor.author | Eberlin, M. N. | |
| dc.contributor.author | Cagnon, JR | |
| dc.contributor.author | Urbano, L. H. | |
| dc.contributor.institution | Universidade Estadual de Campinas (UNICAMP) | |
| dc.contributor.institution | Universidade Estadual Paulista (Unesp) | |
| dc.date.accessioned | 2014-05-20T15:26:47Z | |
| dc.date.available | 2014-05-20T15:26:47Z | |
| dc.date.issued | 2000-01-01 | |
| dc.description.abstract | A new method is described for the rapid, sensitive, virtually interference-free, and selective quantitation of cyanogenic glycosides in aqueous extracts using membrane introduction mass spectrometry (MIMS). Selective monitoring, by either conventional MIMS or cryotrap-MIMS, not of HCN but of the co-released ketones (acetone and butan-2-one), when performed for both the crude cassava extracts and the linamarase-NaOH-hydrolyzed extracts, is found to offer an advantageous alternative to classic spectrophotometric methods based on HCN analysis for the selective quantitation of the two cyanogenic glycosides linamarin and lotaustralin expressed as both the free HCN content and the total cyanogenic potential (total HCN). | en |
| dc.description.affiliation | Univ Estadual Campinas, UNICAMP, Inst Chem, BR-13083970 Campinas, SP, Brazil | |
| dc.description.affiliation | São Paulo State Univ, UNESP, Res Ctr Trop Roots & Starches, CERAT, BR-18603970 Botucatu, SP, Brazil | |
| dc.description.affiliationUnesp | São Paulo State Univ, UNESP, Res Ctr Trop Roots & Starches, CERAT, BR-18603970 Botucatu, SP, Brazil | |
| dc.format.extent | 1529-1531 | |
| dc.identifier | http://dx.doi.org/10.1039/b004300l | |
| dc.identifier.citation | Analyst. Cambridge: Royal Soc Chemistry, v. 125, n. 9, p. 1529-1531, 2000. | |
| dc.identifier.dimensions | pub.1013431519 | |
| dc.identifier.doi | 10.1039/b004300l | |
| dc.identifier.issn | 0003-2654 | |
| dc.identifier.issn | 1364-5528 | |
| dc.identifier.orcid | 0000-0003-4868-0618 | |
| dc.identifier.uri | http://hdl.handle.net/11449/36870 | |
| dc.identifier.wos | WOS:000089052700004 | |
| dc.language.iso | eng | |
| dc.publisher | Royal Soc Chemistry | |
| dc.publisher | Royal Society of Chemistry (RSC) | |
| dc.relation.ispartof | Analyst | |
| dc.relation.ispartofjcr | 3.864 | |
| dc.relation.ispartofsjr | 1,249 | |
| dc.rights.accessRights | Acesso restrito | pt |
| dc.source | Web of Science | |
| dc.source | Dimensions | |
| dc.title | A new method for the selective quantitation of cyanogenic glycosides by membrane introduction mass spectrometry | en |
| dc.type | Artigo | pt |
| dcterms.license | http://www.rsc.org/AboutUs/Copyright/LicencetoPublishforjournals.asp | |
| dcterms.rightsHolder | Royal Soc Chemistry | |
| dspace.entity.type | Publication | |
| unesp.author.orcid | 0000-0002-0853-1944[1] |