Logotipo do repositório
 

Publicação:
Thermal behaviour of bambus[6]uril and its chloride caviplex

Página do item simplificado
dc.contributor.authorCicolani, Renato Salviato
dc.contributor.authorJob, Aldo Eloizo [UNESP]
dc.contributor.authorTonin, Fernando Gustavo
dc.contributor.authorCorreia, Henrique Dias
dc.contributor.authorDemets, Gregoire Jean-Francois
dc.contributor.institutionUniversidade de São Paulo (USP)
dc.contributor.institutionUniversidade Estadual Paulista (Unesp)
dc.date.accessioned2019-10-05T21:44:58Z
dc.date.available2019-10-05T21:44:58Z
dc.date.issued2019-05-01
dc.description.abstractThe present paper presents the thermal behaviour of methyl-bambus[6]uril in its anion-free and chlorine-included form. Our study was based on thermogravimetry associated to Fourier-transform infrared spectroscopy and differential scanning calorimetry. The compounds decompose after 300 degrees C and both forms of this macrocycle, contain four hydration water molecules. The main decomposition products are H2O, CO2, NH3 and isocyanic acid as we could detect by FTIR spectroscopy. Finally, we verified that the caviplex loses its chloride ion after 270 degrees C and may produce the anion-free macrocyle upon heating.en
dc.description.affiliationUniv Sao Paulo, FFCLRP, Dept Quim, Ave Bandeirantes 3900, BR-14040901 Ribeirao Preto, SP, Brazil
dc.description.affiliationUniv Estadual Paulista, Fac Ciencias & Tecnol Presidente Prudente, Rua Roberto Simonsen,305 Ctr Educ, BR-19060900 Presidente Prudente, SP, Brazil
dc.description.affiliationUniv Sao Paulo, Fac Zootecnia & Engn Alimentos, Ave Duque de Caxias Norte 225, BR-13635900 Pirassununga, SP, Brazil
dc.description.affiliationUnespUniv Estadual Paulista, Fac Ciencias & Tecnol Presidente Prudente, Rua Roberto Simonsen,305 Ctr Educ, BR-19060900 Presidente Prudente, SP, Brazil
dc.description.sponsorshipFundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)
dc.description.sponsorshipCoordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)
dc.description.sponsorshipConselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)
dc.description.sponsorshipIdFAPESP: 2016-12666-1
dc.description.sponsorshipIdFAPESP: 2017-19595-5
dc.description.sponsorshipIdCNPq: 457264/2014-4
dc.description.sponsorshipIdCNPq: 134552/2015-6
dc.description.sponsorshipIdCNPq: 176793/2017-5
dc.format.extent1195-1199
dc.identifierhttp://dx.doi.org/10.1007/s10973-018-7755-0
dc.identifier.citationJournal Of Thermal Analysis And Calorimetry. Dordrecht: Springer, v. 136, n. 3, p. 1195-1199, 2019.
dc.identifier.doi10.1007/s10973-018-7755-0
dc.identifier.issn1388-6150
dc.identifier.urihttp://hdl.handle.net/11449/186714
dc.identifier.wosWOS:000464699900019
dc.language.isoeng
dc.publisherSpringer
dc.relation.ispartofJournal Of Thermal Analysis And Calorimetry
dc.rights.accessRightsAcesso aberto
dc.sourceWeb of Science
dc.subjectMethyl-bambus[6]uril
dc.subjectThermal behaviour
dc.subjectMacrocycle
dc.subjectCaviplex
dc.titleThermal behaviour of bambus[6]uril and its chloride caviplexen
dc.typeArtigo
dcterms.licensehttp://www.springer.com/open+access/authors+rights?SGWID=0-176704-12-683201-0
dcterms.rightsHolderSpringer
dspace.entity.typePublication
unesp.author.lattes6475585105456744[2]
unesp.author.orcid0000-0003-0158-6333[1]
unesp.author.orcid0000-0002-1979-8257[2]
unesp.departmentFísica, Química e Biologia - FCTpt

Arquivos

Coleções

Presidente Prudente - FCT - Faculdade de Ciências e Tecnologia