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The influence of crystallization route on the SrBi2Nb2O9 thin films

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Abstract

Polycrystalline SrBi2Nb2O9-layered ferroelectric thin films were synthesized on Pt/Ti/SiO2/Si substrate using the polymeric precursors solution. The dip-coated films were specular and crack-free and crystallized during firing at 700 °C. Single-, double-, and triple-layered films were obtained by several dips in the deposition solution, and the influence of crystallization between each dip was studied. Microstructure and morphological evaluation were followed by grazing incident x-ray diffraction (GIXRD), scanning electron microscopy (SEM), and atomic force microscopy (AFM). Multilayered films obtained using the intermediate-crystallized layer route present a dense microstructure with spherical grains, with a preferential orientation in the 〈215〉 direction; films obtained using the intermediate-amorphous layer route are polycrystalline and present elongated grains around 250 nm in size.

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Crystal microstructure, Crystal orientation, Crystallization, Deposition, Ferroelectric materials, Grain size and shape, Morphology, Multilayers, Perovskite, Polycrystalline materials, Strontium compounds, Synthesis (chemical), Grazing incident X ray diffraction (GIXRD) analysis, Dielectric films

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English

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Journal of Materials Research, v. 14, n. 3, p. 1026-1031, 1999.

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