Publicação: Ordered PtSn/C electrocatalyst: A high performance material for the borohydride electrooxidation reaction
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This work used a rotating disc electrode and quasi-steady state polarization curves to investigate the sodium borohydride electrooxidation of ordered intermetallic PtSn/C in alkaline solution. Under similar experimental conditions, PtSn/C proved to be a better electrocatalyst than Pt in an overall process that involved eight electrons. Assays performed in the presence of thiourea and S2− species evidenced that a chemical hydrolysis step took place, followed by electrochemical oxidation of the generated H2. The results presented herein suggest that PtSn/C constitutes a promising electrode material for application in alkaline borohydride fuel cell.
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Borohydride, Electrooxidation, Hydrogen, Kinect, Mechanism, PtSn/C
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Inglês
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Catalysts, v. 7, n. 7, 2017.
