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Novel stereoselective addition of some nucleophiles to 2,3-bis(methylsulfanyl) norbornenobenzoquinone

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Authors

Wladislaw, B.
DiVitta, C.
Marzorati, L.
Campos, IPD
Lucchini, V

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Undergraduate course

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Elsevier B.V.

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Article

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Abstract

2,3-Bis(methylsulfanyl)norbomenobenzoquinone undergoes reaction with nitrogen, oxygen, sulfur or carbon nucleophiles to give the trisubstituted adducts containing the new substituent at the ring junction. Their configurations are assigned by H-1 NMR spectroscopy and NOE enhancement experiments. (C) 1997 Elsevier B.V. Ltd.

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English

Citation

Tetrahedron Letters. Oxford: Pergamon-Elsevier B.V., v. 38, n. 15, p. 2625-2628, 1997.

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