Publicação: Molecular and crystal structure of trans-(dicyanato)-bis(triphenylphosphine)palladium(II)
| dc.contributor.author | Cristante, Valtair M. [UNESP] | |
| dc.contributor.author | Mauro, Antonio Eduardo [UNESP] | |
| dc.contributor.author | Netto, Adelino V.G. [UNESP] | |
| dc.contributor.author | Frem, Regina C.G. [UNESP] | |
| dc.contributor.author | Ferreira, Janaína G. | |
| dc.contributor.author | Santos, Regina H.A. | |
| dc.contributor.author | Dos Santos, Miriam P. | |
| dc.contributor.institution | Universidade Estadual Paulista (Unesp) | |
| dc.contributor.institution | Universidade de São Paulo (USP) | |
| dc.date.accessioned | 2014-05-27T11:23:48Z | |
| dc.date.available | 2014-05-27T11:23:48Z | |
| dc.date.issued | 2008-12-01 | |
| dc.description.abstract | The triphenylphosphine (PPh3) displaces the acetonitrile from [PdCl2(CH3CN)2], and subsequent addition of the potassium cyanate causes substitution of the chloro ligand by NCO- to yield trans-[Pd(NCO)2(PPh3)2]. The complex was characterized by elemental analysis, IR spectroscopy and single-crystal X-ray diffraction. The title compound was crystallized in a triclinic system, space group P1 with a = 9.213(3)Å, b = 9.781(7)Å, c = 10.483(5)Å, α = 111.39(5)°, β = 93.49(3)°, γ = 103.81(4)°, V = 845.0(1)Å3, Z = 1. The coordination geometry around Pd(II) in this complex is nearly square-planar, with the ligands in a trans relationship. 2008 © The Japan Society for Analytical Chemistry. | en |
| dc.description.affiliation | Departamento de Química Geral e Inorgânica Instituto de Química de Araraquara-UNESP, C. P. 355, CEP 14801-970, Araraquara, S. P | |
| dc.description.affiliation | Departamento de Química e Física Molecular Instituto de Química-USP, C. P. 780, CEP 13560-970, São Carlos, S. P. | |
| dc.description.affiliationUnesp | Departamento de Química Geral e Inorgânica Instituto de Química de Araraquara-UNESP, C. P. 355, CEP 14801-970, Araraquara, S. P | |
| dc.identifier | http://www.jsac.or.jp/cgi-bin/xraystruct/j-abst/24/7/x147/ | |
| dc.identifier.citation | Analytical Sciences: X-ray Structure Analysis Online, v. 24, n. 7, 2008. | |
| dc.identifier.issn | 1348-2238 | |
| dc.identifier.lattes | 3300223970814448 | |
| dc.identifier.lattes | 7927677053650819 | |
| dc.identifier.orcid | 0000-0002-0057-7964 | |
| dc.identifier.scopus | 2-s2.0-70649094157 | |
| dc.identifier.uri | http://hdl.handle.net/11449/70798 | |
| dc.language.iso | eng | |
| dc.relation.ispartof | Analytical Sciences: X-ray Structure Analysis Online | |
| dc.rights.accessRights | Acesso restrito | |
| dc.source | Scopus | |
| dc.title | Molecular and crystal structure of trans-(dicyanato)-bis(triphenylphosphine)palladium(II) | en |
| dc.type | Nota | |
| dspace.entity.type | Publication | |
| unesp.author.lattes | 3300223970814448[2] | |
| unesp.author.lattes | 7927677053650819[3] | |
| unesp.author.orcid | 0000-0002-0057-7964[3] | |
| unesp.campus | Universidade Estadual Paulista (UNESP), Instituto de Química, Araraquara | pt |
| unesp.department | Química Inorgânica - IQAR | pt |