Publicação: Magnetic nanostructured material as heterogeneous catalyst for degradation of AB210 dye in tannery wastewater by electro-Fenton process
Carregando...
Data
Orientador
Coorientador
Pós-graduação
Curso de graduação
Título da Revista
ISSN da Revista
Título de Volume
Editor
Tipo
Artigo
Direito de acesso
Resumo
Degradation of the Acid Black 210 dye (AB210) in synthetic and industrial effluent samples was performed, for the first time, using a heterogeneous electro-Fenton (EF) process with a CoFe2O4/NOM magnetic hybrid catalyst (Hb200). The technique was compared with electrochemical oxidation using electrogenerated hydrogen peroxide (AO-H2O2). The catalyst was synthesized by the sol-gel technique, using water with a high content of natural organic matter (NOM) as an eco-friendly solvent. Analyses using XRD, FTIR, and TEM showed the formation of hybrid nanostructures with average size of 4.85 nm. Electrochemical assays were performed with a GDE/BDD electrode pair, electrogenerated H2O2, and current density of 45.4 mA cm−2. For the synthetic solution of AB210 at pH 3, the EF process presented higher efficiency, compared to AO-H2O2, with the optimum condition achieved using a lower mass of the catalyst (30 mg) and a higher concentration of the dye (55 mg L−1). The EF method also showed superior performance in the treatment of an industrial effluent with high organic load, at pH 6, with almost complete mineralization of AB210 (95%) in 7 h, while the AO-H2O2 process achieved 82% mineralization. The Hb200 hybrid maintained excellent catalytic activity during reuse in 3 cycles, with only 10% lower mineralization efficiency in the last cycle. GC-MS analysis showed that most of the contaminants in the effluent, including bis(2-ethylhexyl) phthalate, one of the most toxic, were eliminated or transformed after the EF treatment with Hb200.
Descrição
Palavras-chave
Azo dye, BDD anode, Cobalt ferrite, Effluent, Mineralization
Idioma
Inglês
Como citar
Chemosphere, v. 280.
