Publication: A 2D coordination polymer with brick-wall network topology based on the [Cu(NCS)(2)(pn)] monomer
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Undergraduate course
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Publisher
Elsevier B.V.
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Article
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Abstract
The new complex [Cu(NCS)(2)(pn)] (1) (pn = 1,3-propanediamine) has been synthesized and characterized by elemental analysis, infrared and electronic spectroscopy. Single crystal X-ray diffraction studies revealed that complex 1 is made up of neutral [Cu(NCS)(2)(pn)] units which are connected by mu-1,3,3-thiocyanato groups to yield a 2D metal-organic framework with a brick-wall network topology. Intermolecular hydrogen bonds of the type NH...SCN and NH...NCS are also responsible for the stabilization of the crystal structure. (c) 2007 Elsevier B.V. All rights reserved.
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Keywords
supramolecular chemistry, self-assembly, copper(II), coordination polymer, hydrogen bonding
Language
English
Citation
Inorganic Chemistry Communications. Amsterdam: Elsevier B.V., v. 10, n. 7, p. 815-820, 2007.
