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A 2D coordination polymer with brick-wall network topology based on the [Cu(NCS)(2)(pn)] monomer

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dc.contributor.authorLegendre, A. O.
dc.contributor.authorMauro, A. E.
dc.contributor.authorFerreira, J. G.
dc.contributor.authorAnanias, S. R.
dc.contributor.authorSantos, R. H A
dc.contributor.authorNetto, Adelino V. G.
dc.contributor.institutionUniversidade Estadual Paulista (Unesp)
dc.contributor.institutionUniversidade de São Paulo (USP)
dc.date.accessioned2014-05-20T15:24:42Z
dc.date.available2014-05-20T15:24:42Z
dc.date.issued2007-07-01
dc.description.abstractThe new complex [Cu(NCS)(2)(pn)] (1) (pn = 1,3-propanediamine) has been synthesized and characterized by elemental analysis, infrared and electronic spectroscopy. Single crystal X-ray diffraction studies revealed that complex 1 is made up of neutral [Cu(NCS)(2)(pn)] units which are connected by mu-1,3,3-thiocyanato groups to yield a 2D metal-organic framework with a brick-wall network topology. Intermolecular hydrogen bonds of the type NH...SCN and NH...NCS are also responsible for the stabilization of the crystal structure. (c) 2007 Elsevier B.V. All rights reserved.en
dc.description.affiliationUNESP, Inst Quim Araraquara, BR-14801970 Araraquara, SP, Brazil
dc.description.affiliationUSP, Inst Quim Sao Carlos, BR-13560970 Sao Carlos, SP, Brazil
dc.description.affiliationUnespUNESP, Inst Quim Araraquara, BR-14801970 Araraquara, SP, Brazil
dc.format.extent815-820
dc.identifierhttp://dx.doi.org/10.1016/j.inoche.2007.04.005
dc.identifier.citationInorganic Chemistry Communications. Amsterdam: Elsevier B.V., v. 10, n. 7, p. 815-820, 2007.
dc.identifier.doi10.1016/j.inoche.2007.04.005
dc.identifier.issn1387-7003
dc.identifier.lattes7927677053650819
dc.identifier.orcid0000-0002-0057-7964
dc.identifier.urihttp://hdl.handle.net/11449/35270
dc.identifier.wosWOS:000247795000020
dc.language.isoeng
dc.publisherElsevier B.V.
dc.relation.ispartofInorganic Chemistry Communications
dc.relation.ispartofjcr1.810
dc.relation.ispartofsjr0,430
dc.rights.accessRightsAcesso restritopt
dc.sourceWeb of Science
dc.subjectsupramolecular chemistrypt
dc.subjectself-assemblypt
dc.subjectcopper(II)pt
dc.subjectcoordination polymerpt
dc.subjecthydrogen bondingpt
dc.titleA 2D coordination polymer with brick-wall network topology based on the [Cu(NCS)(2)(pn)] monomeren
dc.typeArtigopt
dcterms.licensehttp://www.elsevier.com/about/open-access/open-access-policies/article-posting-policy
dcterms.rightsHolderElsevier B.V.
dspace.entity.typePublication
unesp.author.lattes7927677053650819[6]
unesp.author.lattes3123518117881050[1]
unesp.author.lattes3300223970814448[2]
unesp.author.orcid0000-0002-0057-7964[6]
unesp.author.orcid0000-0002-2794-5763[1]
unesp.campusUniversidade Estadual Paulista (UNESP), Instituto de Química, Araraquarapt

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Araraquara - IQAR - Instituto de Química