Publicação: Magnetic oxides of spinel structure: Study of CoxCuyMnzO4 and MgxNiyMnzO4 manganites (x+y+z=3)
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2006-10-01
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Elsevier B.V.
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Systematic studies in manganites of spinel structure have been undertaken. We report on the magnetic properties of two particular cases, in which one of the transition metals, Mg2+ is non-magnetic (NiMgxMn2-xO4) or presents a stable oxidation state, Cu2+ (CoxCuyMnzO4, x + y + z = 3). The magnetic behaviour is described with respect to varying contents of cobalt, copper or manganese. A ferrimagnetic transition is observed at 110-120 K, which depends on the cobalt content. Presence of copper increases the coercive field by a factor of ten with respect to the parent compound NiMn2O4. (c) 2006 Elsevier B.V. All rights reserved.
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Physica B-condensed Matter. Amsterdam: Elsevier B.V., v. 384, n. 1-2, p. 94-96, 2006.