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Self-assembly of metallosupramolecules directed by (N-H)(2)center dot center dot center dot SCN-M (M = Co, Ni), C-H center dot center dot center dot pi and pi-pi synthons

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dc.contributor.authorTakahashi, P. M.
dc.contributor.authorMelo, L. P.
dc.contributor.authorFrem, RCG
dc.contributor.authorNetto, AVG
dc.contributor.authorMauro, Antonio Eduardo [UNESP]
dc.contributor.authorSantos, RHA
dc.contributor.authorFerreira, J. G.
dc.contributor.institutionUniversidade Estadual Paulista (Unesp)
dc.contributor.institutionUniversidade de São Paulo (USP)
dc.date.accessioned2014-05-20T15:20:21Z
dc.date.available2014-05-20T15:20:21Z
dc.date.issued2006-02-06
dc.description.abstractThis work deals with the synthesis, spectroscopic and structural investigation of pyrazolyl complexes of the type trans-[M(NCS)(2)(HPz)(4)] {M=Co (1), Ni (2); HPz=pyrazole}. Single crystal X-ray studies on 1 and 2 reveal the formation of similar supramolecular arrangements derived from self-assembly of monomers linked together through intermolecular N-H center dot center dot center dot SCN hydrogen bonds, C-H center dot center dot center dot pi interactions and pi-pi stacking. (c) 2005 Elsevier B.V. All rights reserved.en
dc.description.affiliationUNESP, Inst Quim, Dept Quim Geral & Inorgan, BR-14801970 Araraquara, SP, Brazil
dc.description.affiliationUSP, Inst Quim, Dept Quim & Fis Mol, BR-13560970 Sao Carlos, SP, Brazil
dc.description.affiliationUnespUNESP, Inst Quim, Dept Quim Geral & Inorgan, BR-14801970 Araraquara, SP, Brazil
dc.format.extent161-167
dc.identifierhttp://dx.doi.org/10.1016/j.molstruc.2005.08.031
dc.identifier.citationJournal of Molecular Structure. Amsterdam: Elsevier B.V., v. 783, n. 1-3, p. 161-167, 2006.
dc.identifier.doi10.1016/j.molstruc.2005.08.031
dc.identifier.issn0022-2860
dc.identifier.lattes3300223970814448
dc.identifier.lattes8534138813417161
dc.identifier.orcid0000-0003-1574-681X
dc.identifier.urihttp://hdl.handle.net/11449/31675
dc.identifier.wosWOS:000235589000019
dc.language.isoeng
dc.publisherElsevier B.V.
dc.relation.ispartofJournal of Molecular Structure
dc.relation.ispartofjcr2.011
dc.relation.ispartofsjr0,409
dc.rights.accessRightsAcesso restrito
dc.sourceWeb of Science
dc.subjectCo(II) and Ni(II) pyrazolyl complexespt
dc.subjectthiocyanatept
dc.subjectself-assemblypt
dc.subjecthydrogen bondingpt
dc.subjectsupramolecular synthonpt
dc.titleSelf-assembly of metallosupramolecules directed by (N-H)(2)center dot center dot center dot SCN-M (M = Co, Ni), C-H center dot center dot center dot pi and pi-pi synthonsen
dc.typeArtigo
dcterms.licensehttp://www.elsevier.com/about/open-access/open-access-policies/article-posting-policy
dcterms.rightsHolderElsevier B.V.
dspace.entity.typePublication
unesp.author.lattes3300223970814448[5]
unesp.author.lattes8534138813417161[3]
unesp.author.orcid0000-0003-1574-681X[3]
unesp.campusUniversidade Estadual Paulista (UNESP), Instituto de Química, Araraquarapt
unesp.departmentQuímica Inorgânica - IQARpt

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Araraquara - IQAR - Instituto de Química