Análise cristalográfica da solução sólida com estrutura tipo Tungstênio Bronze de niobato de potássio e estrôncio dopado com ferro
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Undergraduate course
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Sociedade Brasileira de Química
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Article
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Acesso aberto
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Abstract
Solid solution of iron doped potassium strontium niobate with KSr2(FeNb4)O15-Δ stoichiometry was prepared by high efficiency ball milling method. Structural characterization was carried out by X-ray diffraction. Crystalline structure was analyzed by the Rietveld refinements using the FullProf software. The results showed a tetragonal system with the tetragonal tungsten bronze structure - TTB (a = 12.4631 (2) Å and c = 3.9322 (6) Å, V = 610.78 (2) ų). In this work, the sites occupancy by the K+, Sr2+ and Fe3+ cations on the TTB structure were determined. NbO6 polihedra distortion and its correlation with the theoretical polarization are discussed.
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Keywords
KSr2(FeNb4)O15-δ solid solution, tetragonal tungsten bronze, Rietveld method
Language
Portuguese
Citation
Química Nova. Sociedade Brasileira de Química, v. 33, n. 5, p. 1071-1076, 2010.
