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Neoaustin: a meroterpene produced by Penicillium sp.

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dc.contributor.authorZukerman-Schpector, Julio
dc.contributor.authorMaganhi, Stella H.
dc.contributor.authorFill, Taicia Pacheco
dc.contributor.authorRodrigues-Fo, Edson
dc.contributor.authorCaracelli, Ignez [UNESP]
dc.contributor.institutionUniversidade Federal de São Carlos (UFSCar)
dc.contributor.institutionUniversidade Estadual Paulista (Unesp)
dc.date.accessioned2014-05-20T13:26:24Z
dc.date.available2014-05-20T13:26:24Z
dc.date.issued2009-03-01
dc.description.abstractThe title meroterpene neoaustin {systematic name: (1'S,2'R,3S,7'R,9'S,11'S,12'R)-11'-hydroxy- 2,2,2',9',12'-pentamethyl-6',15'-dimethylene-2,6-dihydro-13'-oxaspiro[pyran-3,5'-tetracyclo[7.5.1.0(1,11).0(2,7)]pentadecane]-6,10',14'-trione}, C(25)H(30)O(6), comprises five rings, three six-membered and two five-membered. The absolute configuration was established based on [alpha D] = + 166.91 degrees (c 1.21, CH(2)Cl(2)). In the crystal, the molecules are connected into a supramolecular helical chain via O-H center dot center dot center dot O hydrogen bonds reinforced by C-H center dot center dot center dot O contacts.en
dc.description.affiliationUniv Fed Sao Carlos, Dept Chem, BR-13565905 Sao Carlos, SP, Brazil
dc.description.affiliationUNESP, Dept Phys, BR-17033360 Bauru, SP, Brazil
dc.description.affiliationUnespUNESP, Dept Phys, BR-17033360 Bauru, SP, Brazil
dc.description.sponsorshipFundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)
dc.description.sponsorshipConselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)
dc.description.sponsorshipCoordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)
dc.description.sponsorshipIdFAPESP: 08/02531-5
dc.format.extentO612-U2621
dc.identifierhttp://dx.doi.org/10.1107/S1600536809006618
dc.identifier.citationActa Crystallographica Section E-structure Reports Online. Malden: Wiley-blackwell Publishing, Inc, v. 65, p. O612-U2621, 2009.
dc.identifier.doi10.1107/S1600536809006618
dc.identifier.fileWOS000264796100234.pdf
dc.identifier.issn1600-5368
dc.identifier.urihttp://hdl.handle.net/11449/8514
dc.identifier.wosWOS:000264796100234
dc.language.isoeng
dc.publisherWiley-Blackwell Publishing, Inc
dc.relation.ispartofActa Crystallographica Section E: Structure Reports Online
dc.relation.ispartofsjr0,138
dc.rights.accessRightsAcesso aberto
dc.sourceWeb of Science
dc.titleNeoaustin: a meroterpene produced by Penicillium sp.en
dc.typeArtigo
dcterms.licensehttp://journals.iucr.org/services/copyrightpolicy.html
dcterms.rightsHolderWiley-blackwell Publishing, Inc
dspace.entity.typePublication
unesp.author.orcid0000-0003-4305-0326[4]
unesp.author.orcid0000-0003-4945-7485[5]
unesp.author.orcid0000-0003-2191-4074[1]
unesp.campusUniversidade Estadual Paulista (UNESP), Faculdade de Ciências, Baurupt
unesp.departmentFísica - FCpt

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Bauru - FC - Faculdade de Ciências