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Crystallographic and spectroscopic studies on palladium(II) complexes containing pyrazole and thiocyanate ligands

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dc.contributor.authorGodoy Netto, Adelino V. [UNESP]
dc.contributor.authorFrem, Regina C.G. [UNESP]
dc.contributor.authorMauro, Antonio E. [UNESP]
dc.contributor.authorSantos, Regina H.A.
dc.contributor.authorZoia, Jussara R.
dc.contributor.institutionUniversidade Estadual Paulista (Unesp)
dc.contributor.institutionUniversidade de São Paulo (USP)
dc.date.accessioned2014-05-27T11:20:27Z
dc.date.available2014-05-27T11:20:27Z
dc.date.issued2002-04-01
dc.description.abstractMononuclear palladium(II) complexes containing both pyrazole-type ligands and thiocyanate, of general formula [Pd(SCN) 2(L) 2] {L = pyrazole (HPz) and l-phenyl-3-methylpyrazole (phmPz)} have been prepared and characterized by elemental analysis, i.r. and n.m.r. spectroscopy and by single crystal X-ray diffraction methods. The Pd atom in these structures lies on the crystallographic inversion center; in a square-planar coordination geometry made by two sulfur and two nitrogen atoms of the ligands, both in trans positions.en
dc.description.affiliationDepartamento de Química Geral e Inorgânica Instituto de Química-UNESP, Araraquara, SP 14801-970
dc.description.affiliationDepartamento de Química e Física Molecular Instituto de Química de São Carlos USP, São Carlos, SP
dc.description.affiliationUnespDepartamento de Química Geral e Inorgânica Instituto de Química-UNESP, Araraquara, SP 14801-970
dc.format.extent279-283
dc.identifierhttp://dx.doi.org/10.1023/A:1014884601346
dc.identifier.citationTransition Metal Chemistry, v. 27, n. 3, p. 279-283, 2002.
dc.identifier.doi10.1023/A:1014884601346
dc.identifier.issn0340-4285
dc.identifier.scopus2-s2.0-0036536483
dc.identifier.urihttp://hdl.handle.net/11449/66861
dc.identifier.wosWOS:000174584400008
dc.language.isoeng
dc.relation.ispartofTransition Metal Chemistry
dc.relation.ispartofjcr1.261
dc.relation.ispartofsjr0,306
dc.rights.accessRightsAcesso restrito
dc.sourceScopus
dc.subjectAtomsen
dc.subjectComplexationen
dc.subjectCrystallographyen
dc.subjectInfrared spectroscopyen
dc.subjectMolecular structureen
dc.subjectNitrogenen
dc.subjectNuclear magnetic resonance spectroscopyen
dc.subjectSingle crystalsen
dc.subjectSpectroscopic analysisen
dc.subjectSulfuren
dc.subjectX ray diffraction analysisen
dc.subjectPalladium complexesen
dc.subjectPyrazole liganden
dc.subjectThiocyanate liganden
dc.subjectPalladiumen
dc.titleCrystallographic and spectroscopic studies on palladium(II) complexes containing pyrazole and thiocyanate ligandsen
dc.typeArtigo
dcterms.licensehttp://www.springer.com/open+access/authors+rights
dspace.entity.typePublication
unesp.author.lattes3300223970814448[3]
unesp.author.orcid0000-0002-0057-7964[1]

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