Fabrication of polypyrrole nanoparticles using microemulsion polymerization for diferent Py/APS/SDS molar ratios
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Data
2016-01-01
Autores
Santim, Ricardo Hidalgo
de Aquino, Hermes Adolfo [UNESP]
Malmonge, José Antonio [UNESP]
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Resumo
Polypyrrole nanoparticles (PPy) were synthesized by the chemical oxidative microemulsion of pyrrole (Py) monomer using ammonium persulfate (APS) as an oxidant agent and sodium dodecylsulfate (SDS) as a surfactant at 28°C and 0°C. Different Py:APS:SDS molar ratios were used, and the properties of the resulting material were examined by four-probe DC electrical conductivity, ultraviolet-visible-near infrared (UV-vis-Nir), and Fourier-transform infrared (FTIR) spectroscopies as well as field-emission scanning electron microscopy (FESEM). UV-vis-Nir and FTIR spectra show the formation of a polaron band owing to the doping of PPy by SDS. The electrical conductivity and morphology of PPy nanoparticles depend on the synthesis conditions. Electrical conductivity of ~95.3×10-3 S/cm was achieved for PPy synthesized at 0°C. For the same Py:APS:SDS molar ratio, the nanoparticle shape changed from cylindrical to spherical upon simply lowering the synthesis temperature.
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Palavras-chave
Microemulsion polymerization, Nanoparticles, Polypyrrole
Como citar
Materials Science Forum, v. 869, p. 391-395.