Direct determination of arsenobetaine and total As in robalo fish liver and tuna fish candidate reference material by slurry sampling graphite furnace atomic absorption spectrometry (SLS-GF AAS)
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Data
2019-01-01
Autores
Bossu, Carla Maíra [UNESP]
De Oca Carioni, Vivian Montes
Naozuka, Juliana
De Oliveira, Pedro Vitoriano
Nomura, Cassiana Seimi
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Resumo
This work describes a simple and rapid screening method for direct speciation of arsenobetaine (AsB) in tuna fish tissue and total As in tuna fish tissue and robalo liver using SLS-GF AAS. All procedures were proposed after careful optimization of pyrolysis and evaluation of chemical modifiers. Best results for total As were acquired using 25 μg Pd + 15 μg Mg + 0.1% w/v Triton X-100 in tuna fish (4.4 ± 0.3 mg kg-1) and 100 μg Pd + 0.1 % w/v Triton X-100 solution in robalo liver (10.3 ± 0.6 mg kg-1) as chemical modifiers. The direct speciation of AsB (3.6 ± 0.4 mg kg-1) in tuna fish was achieved when 5 μg Pd + 3 μg Mg + 0.1% w/v Triton X-100 was used as a chemical modifier. Accuracy was verified using a tuna fish certified reference material (CRM BCR 627), with statistically equivalent concentrations (Student's t-test) for both total As and AsB.
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1. arsenic 2. direct chemical speciation 3. tuna fish 4. robalo liver 5. reference material
Como citar
Ecletica Quimica, v. 44, n. 2, p. 37-44, 2019.