Synthesis, characterization, thermal studies, and DFT calculations on Pd(II) complexes containing N-methylbenzylamine
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Data
2011-11-01
Autores
Lemos, Sahra C. [UNESP]
Franchi, Silmar J. S. [UNESP]
Netto, Adelino Vieira de Godoy [UNESP]
Mauro, Antonio Eduardo [UNESP]
Treu-Filho, Oswaldo [UNESP]
Frem, Regina Célia Galvão [UNESP]
de Almeida, Eduardo Tonon
Torres, Claudia
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Springer
Resumo
This work describes the synthesis, characterization, and the thermal behavior investigation of four palladium(II) complexes with general formulae [PdX(2)(mba)(2)], in which mba = N-methylbenzylamine and X = OAc(-) (1), Cl(-) (2), Br(-) (3) or I(-) (4). The complexes were characterized by elemental analysis, infrared vibrational spectroscopy, and (1)H nuclear magnetic resonance. The stoichiometry of the complexes was established by means of elemental analysis and thermogravimetry (TG). TG/DTA curves showed that the thermodecomposition of the four complexes occurred in 3-4 steps, leading to metallic palladium as final residue. The palladium content found in all curves was in agreement with the mass percentages calculated for the complexes. The following thermal stability sequence was found: 3 > 2 > 4 > 1. The geometry optimization of 1, 2, 3, and 4, calculated using the DFT/B3LYP method, yielded a slightly distorted square planar environment around the Pd(II) ion made by two anionic groups and two nitrogen atoms from the mba ligand (N1 and N2), in a trans-relationship.
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Palladium(II), N-Methylbenzylamine, DFT, TG and DTA
Como citar
Journal of Thermal Analysis and Calorimetry. Dordrecht: Springer, v. 106, n. 2, p. 391-397, 2011.