Solution infrared spectroscopy investigation of copper (II) azide-complexes.
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Data
1996-01-01
Autores
Sargentelli, V
Mauro, Antonio Eduardo [UNESP]
Neto, VAD
Título da Revista
ISSN da Revista
Título de Volume
Editor
Editora Unesp
Resumo
The structure of the two azide-complexes, [Cu(N-3)(2)(N,N-diEten)](2) and [Cu(N-3)(2)(tmeen)](2), N,N-diEten=N,N-diethylethylenediamine; tmeen=N,N,N',N'-tetramethyethylenediamine in solutions of acetonitrile, acetone, tetrahydrofuran, chloroform and dichloromethane, were investigated by infrared spectroscopy. The data show that the complex [Cu(N-3)(2)(N,N-diEten)](2) mantains its structure in solution, while that for [Cu(N-3)(2)(tmeen)](2) is modified.
Descrição
Palavras-chave
azide, infrared copper complexes
Como citar
Ecletica Química. São Paulo: Editora Unesp, v. 21, p. 89-96, 1996.