Nitrosyl ruthenium complexes with general formula [RuCl3,(NO)(P-P)] (P-P={PPh(2)(CH2)(n)PPh(2)},n=1-3 and {PPh(2)-CH=CH-PPh(2)}). X-ray structure of [RuCl3(NO){PPh(2)(CH2)(3)PPh(2)}]
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Data
1997-01-01
Autores
Batista, A. A.
Pereira, C.
Queiroz, S. L.
deOliveira, LAA
Santos, RHD
Gambardella, MTD
Título da Revista
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Título de Volume
Editor
Elsevier B.V.
Resumo
Ruthenium(II) complexes with general formula [RuCl3(NO)(P-P)] were obtained in the solid state, where P-P = PPh(2)(CH2)(n)PPh(2) (n = 1-3) and PPh(2)-CH = CH-PPh(2). The P-31 NMR spectra of these compounds measured in CH2Cl2 showed only singlets, consistent with a fac configuration containing two equivalent phosphorus atoms, However the X-ray diffraction data show that the [RuCl3(NO){PPh(2)(CH2)(3)PPh(2)}] complex crystallizes in a met configuration, where one of the phosphorus atoms is trans to the NO group, in a slightly distorted octahedral geometry. Copyright (C) 1996 Elsevier B.V. Ltd
Descrição
Palavras-chave
ruthenium, nitrosyl, complexes, biphosphines, X-ray structure, isomerism
Como citar
Polyhedron. Oxford: Pergamon-Elsevier B.V., v. 16, n. 6, p. 927-931, 1997.