Growth of calcium phosphate coating on Ti-7.5Mo alloy after anodic oxidation
MetadataShow full item record
Titanium and its alloys are widely used as biomaterials due to their mechanical, chemical and biological properties. To enhance the biocompatibility of titanium alloys, various surface treatments have been proposed. In particular, the formation of titanium oxide nanotubes layers has been extensively examined. Among the various materials for implants, calcium phosphates and hydroxyapatite are widely used clinically. In this work, titanium nanotubes were fabricated on the surface of Ti-7.5Mo alloy by anodization. The samples were anodized for 20 V in an electrolyte containing glycerol in combination with ammonium fluoride (NH4F, 0.25%), and the anodization time was 24 h. After being anodized, specimens were heat treated at 450 °C and 600°C for 1 h to crystallize the amorphous TiO2 nanotubes and then treated with NaOH solution to make them bioactive, to induce growth of calcium phosphate in a simulated body fluid. Surface morphology and coating chemistry were obtained respectively using, field-emission scanning electron microscopy (FEG-SEM), AFM and X-ray diffraction (XRD). It was shown that the presence of titanium nanotubes induces the growth of a sodium titanate nanolayer. During the subsequent invitro immersion in a simulated body fluid, the sodium titanate nanolayer induced the nucleation and growth of nano-dimensioned calcium phosphate. It was possible to observe the formation of TiO2 nanotubes on the surface of Ti-7.5Mo. Calcium phosphate coating was greater in the samples with larger nanotube diameter. These findings represent a simple surface treatment for Ti-7.5Mo alloy that has high potential for biomedical applications. © (2013) Trans Tech Publications, Switzerland.
How to cite this document
Showing items related by title, author, creator and subject.
Escada, A. L A ; Nakazato, R. Z. ; Claro, A.P.R. Alves (Nanoscience and Nanotechnology Letters, 2013) [Trabalho apresentado em evento]Titanium and its alloys are widely used as biomaterials due to their mechanical, chemical and biological properties. To enhance the biocompatibility of titanium alloys, various surface treatments have been proposed. In ...
Photoelectrocatalysis based on Ti/TiO2 nanotubes removes toxic properties of the azo dyes Disperse Red 1, Disperse Red 13 and Disperse Orange 1 from aqueous chloride samples Ferraz, E. R A; Oliveira, G. A R; Grando, M. D.; Lizier, T. M. ; Zanoni, Maria Valnice Boldrin ; Oliveira, D. P. (Journal of Environmental Management, 2013) [Artigo]This work describes the efficiency of photoelectrocatalysis based on Ti/TiO2 nanotubes in the degradation of the azo dyes Disperse Red 1, Disperse Red 13 and Disperse Orange 1 and to remove their toxic properties, as an ...
Escada, A. L. A. ; Machado, J. P. B.; Schneider, S. G.; Nakazato, Roberto Zenhei ; Claro, A. P. R. Alves (Journal of Nano Research, 2011) [Artigo]Many materials with different surfaces have been developed for dental and orthopedics implants. Among the various materials for implants, titanium and bioactive ones such as calcium phosphates and hydroxyapatite, are widely ...