Self-healing ability based on hydrogen bonds in organic coatings for corrosion protection of AA1200

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dc.contributor.authorNardeli, Jéssica V. [UNESP]
dc.contributor.authorFugivara, Cecílio S. [UNESP]
dc.contributor.authorTaryba, Maryna
dc.contributor.authorMontemor, M. F.
dc.contributor.authorBenedetti, Assis V. [UNESP]
dc.contributor.institutionUniversidade Estadual Paulista (Unesp)
dc.contributor.institutionUniversidade de Lisboa
dc.date.accessioned2020-12-12T02:49:27Z
dc.date.available2020-12-12T02:49:27Z
dc.date.issued2020-12-01
dc.description.abstractBiobased polyurethane coatings derived from vegetable oils, with 2 different compositions, were prepared and applied on the AA1200 aluminum alloy to confer corrosion protection. The influence of the ratio between the polyester (flexible segment) and the prepolymer (rigid segment) was investigated. Infrared spectroscopy studies evidenced the difference between the areas of the bands (–NH) and optical and scanning electron microscopy evidenced the morphological features of the coating surface before and after immersion in aggressive medium. The barrier properties and anti-corrosion performance of the coatings were evaluated by electrochemical impedance spectroscopy and the results revealed an increase of impedance over the immersion time. Localized corrosion studies confirmed the self-healing effect in coatings formulated with the highest content of polyester.en
dc.description.affiliationUniversidade Estadual Paulista-UNESP Instituto de Química
dc.description.affiliationCentro de Química Estrutural CQE Departamento de Engenharia Química DEQ Instituto Superior Técnico Universidade de Lisboa, Av. Rovisco Pais
dc.description.affiliationUnespUniversidade Estadual Paulista-UNESP Instituto de Química
dc.identifierhttp://dx.doi.org/10.1016/j.corsci.2020.108984
dc.identifier.citationCorrosion Science, v. 177.
dc.identifier.doi10.1016/j.corsci.2020.108984
dc.identifier.issn0010-938X
dc.identifier.scopus2-s2.0-85090599148
dc.identifier.urihttp://hdl.handle.net/11449/202085
dc.language.isoeng
dc.relation.ispartofCorrosion Science
dc.sourceScopus
dc.subjectAluminum alloy
dc.subjectBiobased coatings
dc.subjectCorrosion protection
dc.subjectLEIS
dc.subjectSelf-healing
dc.subjectSVET/pH micro-potentiometry
dc.titleSelf-healing ability based on hydrogen bonds in organic coatings for corrosion protection of AA1200en
dc.typeArtigo
unesp.author.lattes1769008264876945[5]
unesp.author.lattes2797127887030838[2]
unesp.author.orcid0000-0002-0243-6639[5]
unesp.author.orcid0000-0002-2288-2601[2]

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Artigos - Físico Química - IQ