Degradation of metallophtalocyanine dye by combined processes of electrochemistry and photoelectrochemistry
dc.contributor.author | Osugi, M. E. | |
dc.contributor.author | Umbuzeiro, G. A. | |
dc.contributor.author | Anderson, M. A. | |
dc.contributor.author | Zanoni, Maria Valnice Boldrin [UNESP] | |
dc.contributor.institution | Universidade Estadual Paulista (Unesp) | |
dc.contributor.institution | CETESB Cia Tecnol Saneamento Ambiental | |
dc.contributor.institution | Univ Wisconsin | |
dc.date.accessioned | 2014-05-20T15:30:13Z | |
dc.date.available | 2014-05-20T15:30:13Z | |
dc.date.issued | 2005-09-05 | |
dc.description.abstract | Photoelectrocatalytic degradation of metallophtalocyanine reactive dye (turquoise blue 15) was performed using a Ti/TiO2 thin film photoanode prepared by sol-get method. Hundred percent of color removal and almost complete mineralization (95% at pH 2 and 85% at pH 8) where achieved after 6 h of photolectrocatalytic oxidation of 2.5 x 10(-5) mol L-1 AT15 dye in Na2SO4 mol L-1 under E = +1.2 V versus SCE. The method limitation occurs at dye concentration higher than 4 x 10-5 mol L-1, where the degradation rate becomes markedly slower. An important improvement in color removal and TOC reduction for 1 x 10(-3) mol L-1 metallophtalocyanine dye was achieved using a combined process. After 4 h of potential controlled electrolysis at -1.2 V on a cathode of platinum followed by 6 h of photoelectrocatalytic oxidation leads to 100% of color removal and 83% of TOC decay and eletrodeposition of 69% of the released copper originally presented as copperphtalocyanine complex, by electrodeposition on the cathode without any other treatment. (C) 2005 Elsevier Ltd. All rights reserved. | en |
dc.description.affiliation | Univ Estadual Paulista, Inst Quim, Dept Quim Analit, BR-14801970 Araraquara, SP, Brazil | |
dc.description.affiliation | CETESB Cia Tecnol Saneamento Ambiental, BR-05459900 São Paulo, Brazil | |
dc.description.affiliation | Univ Wisconsin, Environm Chem & Technol Program, Madison, WI 53706 USA | |
dc.description.affiliationUnesp | Univ Estadual Paulista, Inst Quim, Dept Quim Analit, BR-14801970 Araraquara, SP, Brazil | |
dc.format.extent | 5261-5269 | |
dc.identifier | http://dx.doi.org/10.1016/j.electacta.2005.01.058 | |
dc.identifier.citation | Electrochimica Acta. Oxford: Pergamon-Elsevier B.V., v. 50, n. 25-26, p. 5261-5269, 2005. | |
dc.identifier.doi | 10.1016/j.electacta.2005.01.058 | |
dc.identifier.issn | 0013-4686 | |
dc.identifier.orcid | 0000-0002-2296-1393 | |
dc.identifier.uri | http://hdl.handle.net/11449/39642 | |
dc.identifier.wos | WOS:000232344100052 | |
dc.language.iso | eng | |
dc.publisher | Elsevier B.V. | |
dc.relation.ispartof | Electrochimica Acta | |
dc.relation.ispartofjcr | 5.116 | |
dc.relation.ispartofsjr | 1,439 | |
dc.rights.accessRights | Acesso restrito | |
dc.source | Web of Science | |
dc.subject | cooperphtalocyanine dye | pt |
dc.subject | photoelectrocatalytic oxidation | pt |
dc.subject | Ti/TiO2 electrodes | pt |
dc.title | Degradation of metallophtalocyanine dye by combined processes of electrochemistry and photoelectrochemistry | en |
dc.type | Artigo | |
dcterms.license | http://www.elsevier.com/about/open-access/open-access-policies/article-posting-policy | |
dcterms.rightsHolder | Elsevier B.V. | |
unesp.author.orcid | 0000-0002-2296-1393[4] | |
unesp.campus | Universidade Estadual Paulista (Unesp), Instituto de Química, Araraquara | pt |
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