Preparation of ceramic membranes from surface modified tin oxide nanoparticles

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dc.contributor.authorBelin, S.
dc.contributor.authorSantos, LRB
dc.contributor.authorBriois, V
dc.contributor.authorLusvardi, A.
dc.contributor.authorSantilli, Celso Valentim [UNESP]
dc.contributor.authorPulcinelli, Sandra Helena [UNESP]
dc.contributor.authorChartier, T.
dc.contributor.authorLarbot, A.
dc.contributor.institutionUniversidade Estadual Paulista (Unesp)
dc.contributor.institutionUniv Paris 11
dc.contributor.institutionENSCI
dc.contributor.institutionCNRS
dc.date.accessioned2014-05-20T15:26:55Z
dc.date.available2014-05-20T15:26:55Z
dc.date.issued2003-04-15
dc.description.abstractThe preparation of crack-free SnO2 supported membranes requires the development of new strategies of synthesis capable to allow controlled changes of surface chemistry and to improve the processability of supported layers. In this way, the controlled modification of the SnO2 nanoparticle surface by adding capping molecules like Tiron(R) ((OH)(2)C6H2(SO3Na)(2)) during the sol-gel process was studied, aiming to obtain high performance membranes. Colloidal suspensions were prepared by hydrolyzing SnCl4.5H(2)O aqueous solution with NH4OH in presence of Tiron(R). The effect of the amount of Tiro(R) (from I to 20 wt.%) on the structural features of nanoparticles, powder redispersability and particle-solution interface properties was investigated by X-ray powder diffraction (XRPD), extended X-ray absorption fine structure (EXAFS), quasi-elastic light scattering and electrophoretic mobility measurements. XRPD and EXAFS results showed that the addition of Tiron(R) up to 20 wt.% to colloidal suspensions does not affect the crystallite size of SnO2 primary particles, determined around 2-3 nm. This value is comparable to the hydrodynamic size measured after redispersion of powder prepared with amount of Tiro(R) higher than 7.5 wt.%, indicating the absence of condensation reactions between primary particles after the initial precipitation step. As a consequence the powder with amount of Tiron(R) > 7.5 wt.%, can be fully redispersed in aqueous solution at pH greater than or equal to I I until a nanoparticle concentration of 6 vol.%. The electrophoresis measurements showed a decrease of the isoelectric point by increasing the amount of grafted Tiron(R) at the SnO2 nanoparticle surface, resulting in negatively charged particle-solution interface in all the studied pH range (2-11). These features govern the gelation process favoring the preparation of crack-free SnO2 supported membranes. The control exercised by Tiron(R) modifying agent in the aggregation process allows the fine-tuning of the porosity, from 0.124 to 0.065 cm(3) g(-1), and mean pore size, from 6.4 to 1.9 nm, as the amount of grafted molecules increases from 0 to 10 wt.%. In consequence, the membrane cut-off determined by filtration of polyethylene glycol standard solutions can be screened from 1500 to 3500 g mol(-1). (C) 2002 Elsevier B.V. B.V. All rights reserved.en
dc.description.affiliationUNESP, Inst Quim, BR-14800970 Araraquara, SP, Brazil
dc.description.affiliationUniv Paris 11, LURE, F-91898 Orsay, France
dc.description.affiliationENSCI, SPCTS, UMR 6638, F-87065 Limoges, France
dc.description.affiliationCNRS, Inst Europeen Membranes, UMR 5635, F-34293 Montpellier 5, France
dc.description.affiliationUnespUNESP, Inst Quim, BR-14800970 Araraquara, SP, Brazil
dc.format.extent195-206
dc.identifierhttp://dx.doi.org/10.1016/S0927-7757(02)00548-4
dc.identifier.citationColloids and Surfaces A-physicochemical and Engineering Aspects. Amsterdam: Elsevier B.V., v. 216, n. 1-3, p. 195-206, 2003.
dc.identifier.doi10.1016/S0927-7757(02)00548-4
dc.identifier.issn0927-7757
dc.identifier.lattes5584298681870865
dc.identifier.lattes9971202585286967
dc.identifier.orcid0000-0002-8356-8093
dc.identifier.urihttp://hdl.handle.net/11449/36982
dc.identifier.wosWOS:000182771600019
dc.language.isoeng
dc.publisherElsevier B.V.
dc.relation.ispartofColloids and Surfaces A: Physicochemical and Engineering Aspects
dc.relation.ispartofjcr2.829
dc.relation.ispartofsjr0,753
dc.rights.accessRightsAcesso restrito
dc.sourceWeb of Science
dc.subjectceramic membranespt
dc.subjectpowder redispersionpt
dc.subjectnanoparticlespt
dc.subjectsurface modificationpt
dc.subjectsol-gelpt
dc.titlePreparation of ceramic membranes from surface modified tin oxide nanoparticlesen
dc.typeArtigo
dcterms.licensehttp://www.elsevier.com/about/open-access/open-access-policies/article-posting-policy
dcterms.rightsHolderElsevier B.V.
unesp.author.lattes9971202585286967
unesp.author.lattes5584298681870865[5]
unesp.author.orcid0000-0002-8356-8093[5]
unesp.campusUniversidade Estadual Paulista (Unesp), Instituto de Química, Araraquarapt

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Artigos - Físico Química - IQ