Unsaturated flow effects on solute transport in porous media
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A major contaminant transport process in soils is hydrodynamic dispersion by affecting the spreading and arrival of surface-applied pollutants at underlying groundwater reservoirs. When a soil is unsaturated, hydrodynamic dispersion is very much affected by soil water saturation. Centimeter- and decimeter-scale column experiments were carried out to explore the effects of fluid saturation and particle size on the unsaturated solute dispersivity. Measured in-situ breakthrough curves were analyzed in terms of both classical advection–dispersion and dual-porosity (mobile-immobile) type transport equations. A clear non-monotonic relationship was found between the dispersivity and soil water saturation. The extent of non-monotonicity was more pronounced for a relatively coarse-textured sand compared to a finer sand. This finding has been reported rarely before; it explains some of the inconsistencies of saturation-dispersivity relationships in the literature.
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Dispersion, Dispersivity, Solute transport, Unsaturated zone
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Inglês
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Journal of Hydrology, v. 598.
