Crystal structure of (E)-2-[(2S,5R)-2-isopropyl-5-methylcyclohexylidene]hydrazine-1-carbothioamide

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dc.contributor.authorOliveira, Adriano Bof De
dc.contributor.authorBeck, Johannes
dc.contributor.authorDaniels, Jörg
dc.contributor.authorFarias, Renan Lira De
dc.contributor.authorGodoy Netto, Adelino Vieira De [UNESP]
dc.contributor.institutionUniversidade Federal de Sergipe (UFS)
dc.contributor.institutionUniversität Bonn
dc.contributor.institutionUniversidade Estadual Paulista (UNESP)
dc.date.accessioned2022-04-28T19:00:19Z
dc.date.available2022-04-28T19:00:19Z
dc.date.issued2014-08-06
dc.description.abstractThe title compound, C11H21N3S, consists of a menthone moiety attached to an extended thiosemicarbazone group with the N - N - C - N torsion angle being 11.92 (16)°. The cyclohexane ring has a chair conformation and the conformation about the C=N bond is E. In the crystal, molecules are linked via pairs of N - H⋯S hydrogen bonds, forming chains along the a axis. The absolute structure could be assigned with reference to the starting material, i.e. enantiopure (-)-menthone [Flack parameter = 0.05 (5)].en
dc.description.affiliationDepartamento de Química Universidade Federal de Sergipe, Av. Marechal Rondon s/n
dc.description.affiliationInstitut für Anorganische Chemie Universität Bonn, Gerhard-Domagk-Strasse 1
dc.description.affiliationInstituto de Química Universidade Estadual Paulista, Rua Francisco Degni s/n
dc.description.affiliationUnespInstituto de Química Universidade Estadual Paulista, Rua Francisco Degni s/n
dc.format.extento903-o904
dc.identifierhttp://dx.doi.org/10.1107/S1600536814015980
dc.identifier.citationActa Crystallographica Section E: Structure Reports Online, v. 70, n. 9, p. o903-o904, 2014.
dc.identifier.doi10.1107/S1600536814015980
dc.identifier.issn1600-5368
dc.identifier.scopus2-s2.0-84907017809
dc.identifier.urihttp://hdl.handle.net/11449/220213
dc.language.isoeng
dc.relation.ispartofActa Crystallographica Section E: Structure Reports Online
dc.sourceScopus
dc.subjectcrystal structure
dc.subjecthydrogen-bonding polymer
dc.subjectthiocarbazone
dc.titleCrystal structure of (E)-2-[(2S,5R)-2-isopropyl-5-methylcyclohexylidene]hydrazine-1-carbothioamideen
dc.typeArtigo

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