Thermal behaviour of polymetallic metal carbonyls with Fe-Fe, Fe-Hg and Hg-Hg bonds containing Lewis bases.

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dc.contributor.authorCasagrande, O. D.
dc.contributor.authorMauro, A. E.
dc.contributor.institutionUniversidade Estadual Paulista (Unesp)
dc.date.accessioned2014-05-20T15:29:28Z
dc.date.available2014-05-20T15:29:28Z
dc.date.issued1996-07-01
dc.description.abstractThe thermal behaviour of polymetallic metal carbonyls containing Fe-Fe, Fe-Hg and Hg-Hg bonds and Lewis bases, such as [Fe-3(CO)(8)(L)(2)] (L = 1,10-phenantroline,2,2'-bipyridine), [Fe(CO)(4)(HgCl)(2)] and [Fe(CO)(4)(HgCl)(2)(L)(2)] (L = 1,10-phenantroline,2-quinolinethiol), have been investigated by thermal analysis (TG), Thermal studies give evidence that the thermal decomposition mechanisms and starting temperatures are strongly influenced by the Lewis bases. The thermal decompositions under synthetic air yielded, in all cases, the final solid product Fe2O3 which presence was confirmed by X-ray powder diffraction technique.en
dc.description.affiliationUNIV ESTADUAL PAULISTA,INST QUIM ARARAQUARA,BR-14800900 ARARAQUARA,SP,BRAZIL
dc.description.affiliationUnespUNIV ESTADUAL PAULISTA,INST QUIM ARARAQUARA,BR-14800900 ARARAQUARA,SP,BRAZIL
dc.format.extent357-360
dc.identifierhttp://quimicanova.sbq.org.br/qn/qnol/1996/vol19n4/v19_n4_04.pdf
dc.identifier.citationQuimica Nova. São Paulo: Soc Brasileira Quimica, v. 19, n. 4, p. 357-360, 1996.
dc.identifier.fileWOSA1996VN48600005.pdf
dc.identifier.issn0100-4042
dc.identifier.urihttp://hdl.handle.net/11449/39056
dc.identifier.wosWOS:A1996VN48600005
dc.language.isopor
dc.publisherSoc Brasileira Quimica
dc.relation.ispartofQuímica Nova
dc.relation.ispartofjcr0.646
dc.relation.ispartofsjr0,255
dc.rights.accessRightsAcesso aberto
dc.sourceWeb of Science
dc.subjectpolymetallic metal carbonylspt
dc.subjectthermal analysispt
dc.subjectLewis basespt
dc.titleThermal behaviour of polymetallic metal carbonyls with Fe-Fe, Fe-Hg and Hg-Hg bonds containing Lewis bases.en
dc.typeArtigo
dcterms.licensehttp://www.scielo.br/revistas/qn/iaboutj.htm#03
dcterms.rightsHolderSoc Brasileira Quimica
unesp.author.lattes3300223970814448[2]

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