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Chemical and spectroscopic studies of a new palladium(II) complex with N-acetyl-L-cysteine

dc.contributor.authorCorbi, P. P. [UNESP]
dc.contributor.authorCagnin, F. [UNESP]
dc.contributor.authorMassabni, Antonio Carlos [UNESP]
dc.contributor.institutionCentro Univ Araraquara
dc.contributor.institutionUniversidade Estadual Paulista (Unesp)
dc.date.accessioned2014-05-20T15:32:39Z
dc.date.available2014-05-20T15:32:39Z
dc.date.issued2008-01-01
dc.description.abstractChemical and spectroscopic studies of a new palladium(II) N-acetyl-L-cysteine complex are described. Elemental analyses for the solid complex are consistent with the formula [Pd(C(5)H(8)NO(3)S)(2)] H(2)O or [Pd(NAC)(2)] H(2)O. Solid-state (13)C nuclear magnetic resonance (NMR), UV-Visible (UV-Vis) and infrared (IR) spectroscopic analyses are consistent with coordination of the ligand to palladium(II) through the nitrogen and sulfur atoms in a square-planar geometry. Thermogravimetric and differential thermal analyses confirmed the composition; final residue was identified as metallic palladium.en
dc.description.affiliationCentro Univ Araraquara, Ctr Univ Araraquara, Assoc Sao Bento de Ensino, Dept Ciencias Biol & Saude, BR-14801320 Araraquara, SP, Brazil
dc.description.affiliationUNESP, Univ Estadual Paulista, Inst Quim, Dept Quim Geral & Inorgan, BR-14801970 Araraquara, SP, Brazil
dc.description.affiliationUnespUNESP, Univ Estadual Paulista, Inst Quim, Dept Quim Geral & Inorgan, BR-14801970 Araraquara, SP, Brazil
dc.description.sponsorshipFundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)
dc.description.sponsorshipIdFAPESP: 07/56317-1
dc.description.sponsorshipIdFAPESP: 06/55367-2
dc.description.sponsorshipIdFAPESP: 04/11106-5
dc.format.extent3666-3673
dc.identifierhttp://dx.doi.org/10.1080/00958970802108809
dc.identifier.citationJournal of Coordination Chemistry. Abingdon: Taylor & Francis Ltd, v. 61, n. 22, p. 3666-3673, 2008.
dc.identifier.doi10.1080/00958970802108809
dc.identifier.issn0095-8972
dc.identifier.urihttp://hdl.handle.net/11449/41496
dc.identifier.wosWOS:000260213000015
dc.language.isoeng
dc.publisherTaylor & Francis Ltd
dc.relation.ispartofJournal of Coordination Chemistry
dc.relation.ispartofjcr1.703
dc.relation.ispartofsjr0,371
dc.rights.accessRightsAcesso restrito
dc.sourceWeb of Science
dc.subjectN-acetyl-L-cysteineen
dc.subjectPalladium(II)en
dc.subject(13)C NMRen
dc.subjectInfrared spectroscopyen
dc.subjectUV-Visen
dc.subjectThermal analysisen
dc.titleChemical and spectroscopic studies of a new palladium(II) complex with N-acetyl-L-cysteineen
dc.typeArtigo
dcterms.licensehttp://journalauthors.tandf.co.uk/permissions/reusingOwnWork.asp
dcterms.rightsHolderTaylor & Francis Ltd
unesp.campusUniversidade Estadual Paulista (Unesp), Instituto de Química, Araraquarapt
unesp.departmentQuímica Inorgânica - IQARpt

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