Crystal and molecular structure of dinuclear palladium(II) complex containing nitrogen and phosphorus donor ligands, [Pd2(N3)4(PPh3)2(μ-ted)]

Nenhuma Miniatura disponível




Moro, Antonio C. [UNESP]
Mauro, Antonio Eduardo [UNESP]
Legendre, Alexandre O. [UNESP]
Netto, Adelino Vieira de Godoy [UNESP]
Castellano, Eduardo E.

Título da Revista

ISSN da Revista

Título de Volume



The dinuclear azido-palladium(II) complex [Pd2(N3)4(PPh3)2(μ-ted)], where PPh3 = triphenylphosphine and ted = triethylenediamine, was synthesized and characterized by single-crystal X-ray diffraction. The title compound was crystallized in a triclinic system, space group P1 with a = 11.5875(2)Å, b = 13.0817(3)Å, c = 15.2618(3)Å, α = 93.306(2)°, β =110.040(1)°, γ = 98.486(1)°, V = 2134.95(8)Å3, Z = 2. Each Pd(II) center displays a distorted squareplanar coordination environment formed by two N atoms from two trans terminally coordinated azido groups, one P atom from the phosphine and one N atom from the bridging ted ligand. 2008 © The Japan Society for Analytical Chemistry.



Como citar

Analytical Sciences: X-ray Structure Analysis Online, v. 24, n. 7, 2008.