Judd-Ofelt analysis of Pr3+ ions in fluoroindate glasses: Influence of odd third order intensity parameters

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Flórez, A.
Malta, O. L.
Messaddeq, Younes [UNESP]
Aegerter, M. A.

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In this work an analysis of the Judd-Ofelt phenomenological Ωλ intensity parameters for the Pr3+ ion in fluoroindate glass is made. Different Pr3+ concentrations, namely 1, 2, 3 and 4 mol% are used. The experimental oscillator strengths have been determined from the absorption spectra. A consistent set of parameters is obtained only with the inclusion of odd rank third order intensity parameters and if the band at 21 470 cm-1 is assigned to the 3H4 → 3P1 transition and the 1I6 component is incorporated in the 3H4 → 3P2 transition at 22 700 cm-1.



Absorption spectroscopy, Approximation theory, Glass transition, Ions, Light emission, Mathematical models, Optical glass, Praseodymium, Fluoroindate glass, Judd-Ofelt theory, Odd third order intensity parameters, Oscillator strength, Praseodymium ions, Light absorption

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Journal of Non-Crystalline Solids, v. 213-214, p. 315-320.