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Selectivity of the cyclic carbonate formation by fixation of carbon dioxide into epoxides catalyzed by Lewis bases

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dc.contributor.authorGomes, Caio Ribeiro [UNESP]
dc.contributor.authorFerreira, Daniele Marcondes [UNESP]
dc.contributor.authorLeopoldo Constantino, Carlos J. [UNESP]
dc.contributor.authorPerez Gonzalez, Eduardo R. [UNESP]
dc.contributor.institutionUniversidade Estadual Paulista (Unesp)
dc.date.accessioned2014-05-20T13:23:05Z
dc.date.available2014-05-20T13:23:05Z
dc.date.issued2008-11-24
dc.description.abstractCyclic carbonate and polycarbonate have been selectively obtained with good conversion by coupling carbon dioxide with diglycidylether of bisphenol A. The ruthenium trichloride supported on tetraethylammonium bromide and polyphosphotungstic acid has been found active and selective to produce the corresponding monomeric and polymeric carbonates. These catalysts can be recycled keeping their high product conversion and selectivity. The heteropolyacid itself showed high activity also under supercritical CO(2) conditions to yield polycarbonate. (c) 2008 Elsevier Ltd. All rights reserved.en
dc.description.affiliationUnesp Presidente Prudente, Fac Ciência & Tecnol, Dept Fis Quim & Biol, BR-19060900 Presidente Prudente, SP, Brazil
dc.description.affiliationUnespUnesp Presidente Prudente, Fac Ciência & Tecnol, Dept Fis Quim & Biol, BR-19060900 Presidente Prudente, SP, Brazil
dc.description.sponsorshipFundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)
dc.description.sponsorshipConselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)
dc.format.extent6879-6881
dc.identifierhttp://dx.doi.org/10.1016/j.tetlet.2008.09.101
dc.identifier.citationTetrahedron Letters. Oxford: Pergamon-Elsevier B.V. Ltd, v. 49, n. 48, p. 6879-6881, 2008.
dc.identifier.doi10.1016/j.tetlet.2008.09.101
dc.identifier.issn0040-4039
dc.identifier.urihttp://hdl.handle.net/11449/6899
dc.identifier.wosWOS:000260843500039
dc.language.isoeng
dc.publisherPergamon-Elsevier B.V. Ltd
dc.relation.ispartofTetrahedron Letters
dc.relation.ispartofjcr2.125
dc.relation.ispartofsjr0,683
dc.rights.accessRightsAcesso restrito
dc.sourceWeb of Science
dc.subjectCO(2) captureen
dc.subjectCyclic carbonatesen
dc.subjectPolycarbonateen
dc.subjectSelectivityen
dc.titleSelectivity of the cyclic carbonate formation by fixation of carbon dioxide into epoxides catalyzed by Lewis basesen
dc.typeArtigo
dcterms.licensehttp://www.elsevier.com/about/open-access/open-access-policies/article-posting-policy
dcterms.rightsHolderPergamon-Elsevier B.V. Ltd
dspace.entity.typePublication
relation.isOrgUnitOfPublicationbbcf06b3-c5f9-4a27-ac03-b690202a3b4e
relation.isOrgUnitOfPublication.latestForDiscoverybbcf06b3-c5f9-4a27-ac03-b690202a3b4e
unesp.author.lattes6118325967319836[3]
unesp.author.orcid0000-0002-5921-3161[3]
unesp.campusUniversidade Estadual Paulista (UNESP), Faculdade de Ciências e Tecnologia, Presidente Prudentept
unesp.departmentFísica, Química e Biologia - FCTpt

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