Publication: Characterization and catalytical properties of HZSM5 zeolite modified by niobium.
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Undergraduate course
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Soc Brasileira Quimica
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Article
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Abstract
HZSM5 zeolite was modified by exchanging proton by niobium (V). Several samples were obtained with various degrees of exchange. Pore volumes and acidity were measured to characterize these exchanged zeolites, Catalytic properties were evaluated with two reaction tests: m-xylene transformation and n-heptane cracking, The introduction of niobium on HZSM5 zeolite decreases the diffusion coefficient of 2-methyl-pentane and increases the zeolite acidity. The sample. containing niobium are initially more active in cracking of n-heptane and m-xylene isomerization than HZSM5 alone.
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Keywords
HZSM5 zeolite, niobium exchange, pore volume, acidity
Language
Portuguese
Citation
Quimica Nova. Sao Paulo: Soc Brasileira Quimica, v. 20, n. 1, p. 9-13, 1997.