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H-1 and C-13 NMR of some alpha-halo derivatives of o-xylene

dc.contributor.authorRezende, D. D.
dc.contributor.authorAlcantara, M. R.
dc.contributor.authorCampos, IPD
dc.contributor.authorToscano, V. G.
dc.contributor.authorEbeling, G.
dc.contributor.authorLopes, JCD
dc.contributor.institutionUniversidade de São Paulo (USP)
dc.contributor.institutionUniversidade Estadual Paulista (Unesp)
dc.contributor.institutionUNIV FED RIO GRANDE SUL
dc.contributor.institutionUniversidade Federal de Minas Gerais (UFMG)
dc.date.accessioned2015-03-18T15:54:10Z
dc.date.available2015-03-18T15:54:10Z
dc.date.issued1997-07-21
dc.description.abstractC-13 and H-1 NMR data for a series of alpha-halo derivatives of o-xylene are presented. A dynamic H-1 NMR investigation of alpha,alpha,alpha',alpha'-tetrabromo-o-xylene (5) was performed and the spectrum of the most stable conformer at 213 K is presented. The free energy of activation for the rotation of the CHBr2 groups in 5 are determined for the first time. (C) 1997 Elsevier Science Ltd.en
dc.description.affiliationUNIV SAO PAULO, INST QUIM, BR-05599970 SAO PAULO, BRAZIL
dc.description.affiliationUNIV ESTADUAL PAULISTA, INST CIENCIAS EXATAS & TECNOL, BR-06500000 SANTANA PARNA, SP, BRAZIL
dc.description.affiliationUNIV FED RIO GRANDE SUL, INST QUIM, BR-91501970 PORTO ALEGRE, RS, BRAZIL
dc.description.affiliationUNIV FED MINAS GERAIS, DEPT QUIM, ICEX, BR-31270901 BELO HORIZONTE, MG, BRAZIL
dc.description.affiliationUnespUNIV ESTADUAL PAULISTA, INST CIENCIAS EXATAS & TECNOL, BR-06500000 SANTANA PARNA, SP, BRAZIL
dc.format.extent10113-10122
dc.identifierhttp://dx.doi.org/10.1016/S0040-4020(97)00352-9
dc.identifier.citationTetrahedron. Oxford: Pergamon-elsevier Science Ltd, v. 53, n. 29, p. 10113-10122, 1997.
dc.identifier.doi10.1016/S0040-4020(97)00352-9
dc.identifier.issn0040-4020
dc.identifier.urihttp://hdl.handle.net/11449/116805
dc.identifier.wosWOS:A1997XM15000025
dc.language.isoeng
dc.publisherElsevier B.V.
dc.relation.ispartofTetrahedron
dc.relation.ispartofjcr2.377
dc.relation.ispartofsjr0,800
dc.rights.accessRightsAcesso restrito
dc.sourceWeb of Science
dc.titleH-1 and C-13 NMR of some alpha-halo derivatives of o-xyleneen
dc.typeArtigo
dcterms.licensehttp://www.elsevier.com/about/open-access/open-access-policies/article-posting-policy
dcterms.rightsHolderElsevier B.V.
dspace.entity.typePublication

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