Magnetic properties of poly(3-hexylthiophene)
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Elsevier B.V.
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Article
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Abstract
A room temperature ferromagnetic phase is observed in samples of poly(3-hexylthiophene) partially doped with ClO (4) over bar. The magnetic behavior presents a strong dependence on the sample preparation conditions, in particular, a dependence with the final potential of the sample after reduction. The origin of the ferromagnetism is proposed to be associated with interactions between spin 1/2 polarons formed in the polymeric chain upon doping. The dependence of saturation and spontaneous magnetization as the function of the final potential after reduction shows a way to control the magnetic properties of this polymer. (C) 2008 Elsevier B.V. All rights reserved.
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English
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Journal of Magnetism and Magnetic Materials. Amsterdam: Elsevier B.V., v. 320, n. 14, p. E193-E195, 2008.
