Publicação: Ultraviolet-protective thin film based on PVA–melanin/rod-coated silver nanowires and its application as a transparent capacitor
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Melanin is a biopigment in many organisms with interesting intrinsic properties suitable for emerging and sustainable technologies. In this work, we report the fabrication of transparent ultraviolet (UV)-protective thin films based on synthetic melanin in poly(vinyl alcohol) (PVA) matrixes. Melanin was synthesized through the auto-oxidation of l-3,4-dihydroxyphenylalanine (l-DOPA) under oxygen pressure, resulting in excellent solubility in water. A thin film with a composition of 3 wt % melanin (synthesized at 6 atm oxygen pressure) and silver nanowires (AgNWs) deposited on the surface has good transparency in visible light and 100% UV irradiation photoprotection. Encapsulated PVA–melanin/AgNW films dipped in water for 7 days retained 98% of their UV irradiation photoprotection. Moreover, using a transparent conductive oxide substrate, this UV-protective system can be simultaneously used as a transparent capacitor. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019, 136, 47805.
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blends, films, nanoparticles, nanowires, and nanocrystals, optical and photovoltaic applications, surfaces and interfaces
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Inglês
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Journal of Applied Polymer Science, v. 136, n. 30, 2019.
