On the effects of hydroxyl substitution degree and molecular weight on mechanical and water barrier properties of hydroxypropyl methylcellulose films
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Data
2018-04-01
Autores
Otoni, Caio G.
Lorevice, Marcos V.
Moura, Marcia R. de [UNESP]
Mattoso, Luiz H. C.
Título da Revista
ISSN da Revista
Título de Volume
Editor
Elsevier B.V.
Resumo
In line with the increasing demand for sustainable packaging materials, this contribution aimed to investigate the film-forming properties of hydroxypropyl methylcellulose (HPMC) to correlate its chemical structure with film properties. The roles played by substitution degree (SD) and molecular weight (M-w) on the mechanical and water barrier properties of HPMC films were elucidated. Rheological, thermal, and structural experiments supported such correlations. SD was shown to markedly affect film affinity and barrier to moisture, glass transition, resistance, and extensibility, as hydroxyl substitution lessens the occurrence of polar groups. M-w affected mostly the rheological and mechanical properties of HPMC-based materials. Methocel (R) E4 M led to films featuring the greatest tensile strength (ca., 67 MPa), stiffness (ca., 1.8 GPa), and extensibility (ca., 17%) and the lowest permeability to water vapor (ca., 0.9 g mm kPa(-1) h(-1) m(-2)). These properties, which arise from its longer and less polar chains, are desirable for food packaging materials.
Descrição
Palavras-chave
Biopolymer, Cellulose derivative, Cellulose ether, Hypromellose, Food packaging, Edible film
Como citar
Carbohydrate Polymers. Oxford: Elsevier Sci Ltd, v. 185, p. 105-111, 2018.