Synthesis, characterization, and thermal behavior of palladium(II) coordination compounds containing isonicotinamide
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Data
2011-11-01
Autores
de Souza, Rodrigo A. [UNESP]
Mauro, Antonio Eduardo [UNESP]
Netto, Adelino Vieira de Godoy [UNESP]
da Cunha, Gislaine A. [UNESP]
de Almeida, Eduardo T.
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Título de Volume
Editor
Springer
Resumo
Palladium(II) coordination compounds of general formula trans-[PdX(2)(isn)(2)], X = Cl(-) (1), N(3) (-) (2), SCN(-) (3), NCO(-) (4), isn = isonicotinamide; were synthesized and characterized in solid state by elemental analysis, infrared spectroscopy, and simultaneous TG-DTA. TG experiments reveal that the compounds 1-4 undergo thermal decomposition in three or four stages, yielding Pd(0) as final residue, according to calculus and identification by X-ray powder diffraction.
Descrição
Palavras-chave
Palladium(II), Isonicotinamide, TG-DTA, IR spectroscopy
Como citar
Journal of Thermal Analysis and Calorimetry. Dordrecht: Springer, v. 106, n. 2, p. 375-378, 2011.