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Spectral redistribution of waveguided emission in BEH-PPV films

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Taylor & Francis Ltd

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We report on spectral redistribution of the photoluminescence (PL) emission from the edge of thin-film planar waveguides of the conjugated polymer BEH-PPV [Poly(2,5-bis(2'-ethyl-hexyl)-1,4-phenylenevinylene] induced by self-absorption in the polymer film. The PL spectra present drastic changes and displace to longer wavelengths with increasing self-absorption. We observe an enhancement of the absolute PL intensity at longer wavelengths, which was interpreted as due to re-emission of self-absorbed photons. The significant efficiency for the PL re-emission suggests the use of self-absorption as a mechanism for tuning the emission into the near infrared.

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BEH-PPV, photoluminescence, self-absorption, thin-film waveguides, spectral redistribution, conjugated polymers

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Inglês

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Molecular Crystals and Liquid Crystals. Abingdon: Taylor & Francis Ltd, v. 374, p. 445-450, 2002.

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