REDUCTION OF THE AMIDO-BONDED (2-PICOLINAMIDO)PENTAAMMINERUTHENIUM(III) FOLLOWED BY FORMATION OF CIS-(2-PICOLINAMIDE)TETRAAMMINERUTHENIUM(II)
Nenhuma Miniatura disponível
Data
1994-10-12
Autores
Darocha, Z. N.
Chiericato, G.
Tfouni, E.
Título da Revista
ISSN da Revista
Título de Volume
Editor
Amer Chemical Soc
Resumo
[(NH3)(5)Ru-III(2-NCpy)], obtained from electrochemical oxidation of the Ru(II) complex, undergoes hydrolysis to the amido-bonded [Ru-III(NHC(O)-2-py)]. The electrochemical reduction of this latter complex to Ru(II) is followed by an aquation reaction to form [R(II)(NH3)(5)(OH2)] and free picolinamide and a chelation reaction to form cis-[R(II)-(NH3)(4)(2-pica)] with the displacement of one cis ammonia.
Descrição
Palavras-chave
Como citar
Inorganic Chemistry. Washington: Amer Chemical Soc, v. 33, n. 21, p. 4619-4620, 1994.