Mechanistic study of the formation of multiblock π-conjugated metallopolymer

dc.contributor.authorPeverari, Camila R. [UNESP]
dc.contributor.authorDavid-Parra, Diego N.
dc.contributor.authorBarsan, Madalina M.
dc.contributor.authorTeixeira, Marcos F.S. [UNESP]
dc.contributor.institutionUniversidade Estadual Paulista (Unesp)
dc.contributor.institutionUniversidade de São Paulo (USP)
dc.contributor.institutionUniversity of Coimbra
dc.date.accessioned2018-12-11T16:43:01Z
dc.date.available2018-12-11T16:43:01Z
dc.date.issued2016-01-01
dc.description.abstractElectropolymerization of a π-conjugated polymer from [N,N′-bis(salicylidene)-o-phenylenediamine]nickel(II) complex ([Ni(salophen)]) on the surface of indium-tin-oxide (ITO) was studied. Two structures of the polymer have been proposed based on the theorem of molecular columns. The highlighted structures are the molecular column of the central aromatic rings (MCCAR) and molecular column of the side aromatic rings (MCSAR). The molecular structures were obtained by control of the potential scan rate in the electropolymerization step. The MCCAR structures are stable and structurally compact, whereas the MCSAR structures are less compact. Electrochemical measurements, atomic force microscopy (AFM), UV–Vis spectroscopy, FTIR Raman spectroscopy and optical microscopy support the formation of the multiblock π-conjugated polymer.en
dc.description.affiliationDepartment of Chemistry and Biochemistry Faculty of Science and Technology São Paulo State University (UNESP), Rua Roberto Simonsen 305
dc.description.affiliationSão Carlos Institute of Chemistry University of São Paulo (USP)
dc.description.affiliationDepartment of Chemistry Faculty of Science and Technology University of Coimbra
dc.description.affiliationUnespDepartment of Chemistry and Biochemistry Faculty of Science and Technology São Paulo State University (UNESP), Rua Roberto Simonsen 305
dc.format.extent415-421
dc.identifierhttp://dx.doi.org/10.1016/j.poly.2016.06.021
dc.identifier.citationPolyhedron, v. 117, p. 415-421.
dc.identifier.doi10.1016/j.poly.2016.06.021
dc.identifier.file2-s2.0-84976908759.pdf
dc.identifier.issn0277-5387
dc.identifier.scopus2-s2.0-84976908759
dc.identifier.urihttp://hdl.handle.net/11449/168780
dc.language.isoeng
dc.relation.ispartofPolyhedron
dc.relation.ispartofsjr0,472
dc.rights.accessRightsAcesso aberto
dc.sourceScopus
dc.subjectElectropolymerization
dc.subjectMetallopolymer
dc.subjectMolecular columns
dc.subjectMolecular conductivity
dc.subjectπ-Conjugated polymer
dc.titleMechanistic study of the formation of multiblock π-conjugated metallopolymeren
dc.typeArtigo

Arquivos

Pacote Original
Agora exibindo 1 - 1 de 1
Carregando...
Imagem de Miniatura
Nome:
2-s2.0-84976908759.pdf
Tamanho:
2.06 MB
Formato:
Adobe Portable Document Format
Descrição:

Coleções