Factors which affect the catalytic activity of iron(III) meso tetrakis(2,6-dichlorophenyl)porphyrin chloride in homogeneous system

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dc.contributor.authorIamamoto, Y.
dc.contributor.authorAssis, M. D.
dc.contributor.authorCiuffi, K. J.
dc.contributor.authorSacco, H. C.
dc.contributor.authorIwamoto, L.
dc.contributor.authorMelo, AJB
dc.contributor.authorNascimento, O. R.
dc.contributor.authorPrado, C. M.
dc.contributor.institutionUniversidade de São Paulo (USP)
dc.contributor.institutionUniversidade Estadual Paulista (Unesp)
dc.date.accessioned2014-05-20T15:26:59Z
dc.date.available2014-05-20T15:26:59Z
dc.date.issued1996-07-10
dc.description.abstractAn optimization study of the reaction conditions of Fe(TDCPP)Cl when it is used as catalyst in the hydroxylation of cyclohexane by iodosylbenzene (PhIO) has been carried out, It was found that Fe(TDCPP)Cl follows the classical PhIO mechanism described for Fe(TPP)Cl, which involves the monomeric active species Fe-IV(O)P-+. (I). In the optimized condition ([Fe(TDCPP) = 3.0 X 10(-4) mol l(-1) in 1,2-dichloroethane (DCE); ultrasound stirring at 0 degrees C; PhIO/FeP molar ratio = 100), this FeP led to a yield of cyclohexanol (C-ol) of 96% and a turnover number of 96, Therefore, Fe(TDCPP)Cl may be considered a good biomimetic model and a very stable, resistant and selective catalyst, which yields C-ol as the sole product. DCE showed to be a better solvent than dichloromethane (DCM), 1 DCE:1 MeOH mixture or acetonitrile (ACN). Since the Fe-IV(O)P-+. is capable of abstracting hydrogen atom from DCM, MeOH or ACN, the solvent competes with the substrate. Presence of O-2 lowers the yield of C-ol, as it can further oxidize this alcohol to carboxylic acid in the presence of radicals, Presence of H2O also causes a decrease in the yield, since it converts the active species I into Fe-IV(OH)P, which cannot oxidize cyclohexane. Addition of excess imidazole or OH- to the system results in a decrease in the yield of C-ol, due to the formation of the hexacoordinated complexes Fe(TDCPP)Im(2)(+) (low-spin, beta(2) = 2.5 X 10(8) mol(-2) l(2)) and Fe(TDCPP)(OH)(2)(-) (high-spin, beta(2) = 6.3 X 10(7) mol(-2) l(2)), the formation of both Fe(TDCPP)Im(2)(+) and Fe(TDCPP)(OH)(2)(-) complexes were confirmed by EPR studies. The catalytic activities of Fe(TDCPP)C and Fe(TFPP)Cl were compared, the unusually high yields of C-ol with Fe(TFPP)Cl obtained when ultrasound, DCM and O-2 atmosphere were used, suggest that a parallel mechanism involving the mu-oxo dimer form, O-2 and radicals may also be occurring with this FeP, besides the PhIO mechanism.en
dc.description.affiliationUNIV SAO PAULO,INST FIS SAO CARLOS,BR-13560970 SAO CARLOS,SP,BRAZIL
dc.description.affiliationUNESP,INST QUIM,BR-14800900 ARARAQUARA,SP,BRAZIL
dc.description.affiliationUnespUNESP,INST QUIM,BR-14800900 ARARAQUARA,SP,BRAZIL
dc.format.extent189-200
dc.identifierhttp://dx.doi.org/10.1016/1381-1169(96)00030-1
dc.identifier.citationJournal of Molecular Catalysis A-chemical. Amsterdam: Elsevier B.V., v. 109, n. 3, p. 189-200, 1996.
dc.identifier.doi10.1016/1381-1169(96)00030-1
dc.identifier.issn1381-1169
dc.identifier.urihttp://hdl.handle.net/11449/37048
dc.identifier.wosWOS:A1996UX57700001
dc.language.isoeng
dc.publisherElsevier B.V.
dc.relation.ispartofJournal of Molecular Catalysis A: Chemical
dc.relation.ispartofjcr4.397
dc.rights.accessRightsAcesso restrito
dc.sourceWeb of Science
dc.subjectcyclohexanept
dc.subjectiron(III)porphyrinpt
dc.subjectoxidationpt
dc.subjectporphyrinpt
dc.subject2,6-dichlorophenylporphyrinpt
dc.subjectpentafluorophenylporphyrinpt
dc.subjecthomogeneous catalysispt
dc.titleFactors which affect the catalytic activity of iron(III) meso tetrakis(2,6-dichlorophenyl)porphyrin chloride in homogeneous systemen
dc.typeArtigo
dcterms.licensehttp://www.elsevier.com/about/open-access/open-access-policies/article-posting-policy
dcterms.rightsHolderElsevier B.V.
unesp.author.orcid0000-0001-8270-0286[3]
unesp.author.orcid0000-0003-0761-5086[1]

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