Hydrogen Peroxide Electrogeneration by Gas Diffusion Electrode Modified with Tungsten Oxide Nanoparticles for Degradation of Orange II and Sunset Yellow FCF Azo Dyes

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Paz, Edson C.
Pinheiro, Victor S.
Aveiro, Luci R.
Souza, Fernanda L.
Lanza, Marcos R. [UNESP]
Santos, Mauro G.

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Soc Brasileira Quimica


In this work, the gas diffusion electrode (GDE) cathode of Vulcan XC72 carbon modified with nanoparticles of WO2.72 (WO2.72 / Vulcan XC72) was used for H2O2 electrogeneration and degradation of 350 mL of Orange II (OH) and Sunset Yellow FCF (SY) azo dyes by electro-Fenton (EF) and photoelectro-Fenton (PEF) processes with different Fe2+ initial content (1.00, 0.50 and 0.25 mmol L-1). The WO2.72 / Vulcan XC72 GDE electrolyzed approximately 3 times more H2O2 than the Vulcan XC72 GDE. Decolorizations and mineralizations of the dye solutions were more efficient at higher concentrations of Fe2+. The decolorization decay showed pseudo-first-order kinetics. The most promising decolorization results obtained at processes of WO2.72 / Vulcan XC72 cathode combined with Pt anode (100% color removal of OII and SY at 30 and 20 min of electrolysis with 1.00 mmol L-1 Fe2+, respectively). The best mineralization achieved in trials of WO2.72 / Vulcan XC72 cathode combined with boron-doped diamond (BDD) anode (82% total organic carbon (TOC) removal of OII by PEF / 1.00 after 3 h and 90% TOC removal of SY by PEF / 050 after 4 h). It was found that SY decolorization was faster and mineralization showed a similar yield independent of oxidized dye.



WO2.72 / Vulcan XC72, H2O electrogeneration, decolorization, mineralization, azo dyes

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Journal Of The Brazilian Chemical Society. Sao Paulo: Soc Brasileira Quimica, v. 30, n. 9, p. 1964-1975, 2019.