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Thermal and spectroscopic studies on solid ibuprofen complexes of lighter trivalent lanthanides

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dc.contributor.authorGalico, D. A. [UNESP]
dc.contributor.authorHolanda, B. B. C. [UNESP]
dc.contributor.authorGuerra, R. B. [UNESP]
dc.contributor.authorLegendre, Alexandre de Oliveira [UNESP]
dc.contributor.authorRinaldo, Daniel [UNESP]
dc.contributor.authorTreu-Filho, O. [UNESP]
dc.contributor.authorBannach, Gilbert [UNESP]
dc.contributor.institutionUniversidade Estadual Paulista (Unesp)
dc.date.accessioned2014-12-03T13:09:13Z
dc.date.available2014-12-03T13:09:13Z
dc.date.issued2014-01-10
dc.description.abstractSolid-state compounds of general formula Ln(L)(3), in which Lis ibuprofen and Ln stands for trivalent La, Ce, Pr, Nd, Sm and Eu, have been synthesized. Simultaneous thermogravimetry and differential thermal analysis (TG-DTA), X-ray powder diffractometry (DRX), complexometry, Fourier-transformed infrared spectroscopy (FTIR) and thermogravimetry coupled to Fourier-transformed infrared spectroscopy (TG-FTIR) were used to characterize these compounds. The results provided information concerning the chemical composition, dehydration, coordination modes of the ligands, crystallinity of the samples, thermal behavior and thermal decomposition of the compounds. The theoretical and experimental spectroscopic studies suggest that ibuprofen coordinates through the carboxylate group as a chelating ligand. (C) 2013 Elsevier B.V. All rights reserved.en
dc.description.affiliationUNSEP Univ Estadual Paulista, Fac Ciancias, Dept Quim, BR-17033260 Sao Paulo, Brazil
dc.description.affiliationUNSEP Univ Estadual Paulista, Inst Quim, BR-14800900 Sao Paulo, Brazil
dc.description.affiliationUnespUNESP Univ Estadual Paulista, Fac Ciancias, Dept Quim, BR-17033260 Sao Paulo, Brazil
dc.description.affiliationUnespUNSEP Univ Estadual Paulista, Inst Quim, BR-14800900 Sao Paulo, Brazil
dc.description.sponsorshipFundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)
dc.description.sponsorshipConselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)
dc.description.sponsorshipIdFAPESP: 12/21450-1
dc.format.extent226-232
dc.identifierhttp://dx.doi.org/10.1016/j.tca.2013.11.005
dc.identifier.citationThermochimica Acta. Amsterdam: Elsevier Science Bv, v. 575, p. 226-232, 2014.
dc.identifier.doi10.1016/j.tca.2013.11.005
dc.identifier.issn0040-6031
dc.identifier.urihttp://hdl.handle.net/11449/112093
dc.identifier.wosWOS:000329889500030
dc.language.isoeng
dc.publisherElsevier B.V.
dc.relation.ispartofThermochimica Acta
dc.relation.ispartofjcr2.189
dc.relation.ispartofsjr0,605
dc.rights.accessRightsAcesso restrito
dc.sourceWeb of Science
dc.subjectIbuprofenen
dc.subjectLanthanidesen
dc.subjectCarboxylate complexesen
dc.subjectThermal behavioren
dc.subjectInfrared spectroscopyen
dc.subjectTG-FTIRen
dc.titleThermal and spectroscopic studies on solid ibuprofen complexes of lighter trivalent lanthanidesen
dc.typeArtigo
dcterms.licensehttp://www.elsevier.com/about/open-access/open-access-policies/article-posting-policy
dcterms.rightsHolderElsevier B.V.
dspace.entity.typePublication
unesp.author.lattes3123518117881050[4]
unesp.author.orcid0000-0002-2794-5763[4]
unesp.author.orcid0000-0001-5363-6481[5]
unesp.author.orcid0000-0002-8790-5069[7]
unesp.campusUniversidade Estadual Paulista (Unesp), Faculdade de Ciências, Baurupt
unesp.departmentQuímica - FCpt

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Bauru - FC - Faculdade de Ciências