Effect of Er3+ ions on the phase formation and properties of In(2)O(3)nanostructures crystallized upon microwave heating

dc.contributor.authorLemos, Samantha C. S.
dc.contributor.authorRomeiro, Fernanda C.
dc.contributor.authorPaula, Leonardo F. de
dc.contributor.authorGoncalves, Rosana F.
dc.contributor.authorMoura, Ana P. de [UNESP]
dc.contributor.authorFerrer, Mateus M.
dc.contributor.authorLongo, Elson
dc.contributor.authorPatrocinio, Antonio Otavio T.
dc.contributor.authorLima, Renata C.
dc.contributor.institutionUniversidade Federal de Uberlândia (UFU)
dc.contributor.institutionUniversidade Federal de São Paulo (UNIFESP)
dc.contributor.institutionUniversidade Estadual Paulista (Unesp)
dc.contributor.institutionUniversidade Federal de São Carlos (UFSCar)
dc.date.accessioned2018-11-26T15:44:03Z
dc.date.available2018-11-26T15:44:03Z
dc.date.issued2017-05-01
dc.description.abstractRegular sized nanostructures of indium oxide (In2O3) were homogeneously grown using a facile route, i.e. a microwave-hydrothermal method combined with rapid thermal treatment in a microwave oven. The presence of Er3+ doping plays an important role in controlling the formation of cubic (bcc) and rhombohedral (rh) In2O3 phases. The samples presented broad photoluminescent emission bands in the green-orange region, which were attributed to the recombination of electrons at oxygen vacancies. The photocatalytic activities of pure bcc-In2O3 and a bcc-rh-In2O3 mixture towards the UVA degradation of methylene blue (MB) were also evaluated. The results showed that Er+3 doped In2O3 exhibited the highest photocatalytic activity with a photonic efficiency three times higher than the pure oxide. The improved performance was attributed to the higher surface area, the greater concentration of electron traps due the presence of the dopant and the possible formation of heterojunctions between the cubic and rhombohedral phases.en
dc.description.affiliationUniv Fed Uberlandia, Inst Quim, BR-38400902 Uberlandia, MG, Brazil
dc.description.affiliationUniv Fed Sao Paulo, UNIFESP, BR-09972270 Diadema, SP, Brazil
dc.description.affiliationUniv Estadual Paulista, Inst Quim, LIEC, BR-14800900 Araraquara, SP, Brazil
dc.description.affiliationUniv Fed Sao Carlos, INCTMN UFSCar, BR-13565905 Sao Carlos, SP, Brazil
dc.description.affiliationUnespUniv Estadual Paulista, Inst Quim, LIEC, BR-14800900 Araraquara, SP, Brazil
dc.description.sponsorshipCoordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)
dc.description.sponsorshipConselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)
dc.description.sponsorshipFundação de Amparo à Pesquisa do Estado de Minas Gerais (FAPEMIG)
dc.description.sponsorshipIdFAPEMIG: APQ-00988-13
dc.description.sponsorshipIdFAPEMIG: APQ-00330-14
dc.description.sponsorshipIdFAPEMIG: CEX - RED-00010-14
dc.format.extent58-63
dc.identifierhttp://dx.doi.org/10.1016/j.jssc.2017.02.011
dc.identifier.citationJournal Of Solid State Chemistry. San Diego: Academic Press Inc Elsevier Science, v. 249, p. 58-63, 2017.
dc.identifier.doi10.1016/j.jssc.2017.02.011
dc.identifier.fileWOS000398879700010.pdf
dc.identifier.issn0022-4596
dc.identifier.urihttp://hdl.handle.net/11449/159499
dc.identifier.wosWOS:000398879700010
dc.language.isoeng
dc.publisherElsevier B.V.
dc.relation.ispartofJournal Of Solid State Chemistry
dc.relation.ispartofsjr0,632
dc.rights.accessRightsAcesso aberto
dc.sourceWeb of Science
dc.subjectIndium oxide
dc.subjectEarth rare
dc.subjectMicrowave hydrothermal
dc.subjectPhotoluminescence
dc.subjectPhotocatalyst
dc.titleEffect of Er3+ ions on the phase formation and properties of In(2)O(3)nanostructures crystallized upon microwave heatingen
dc.typeArtigo
dcterms.licensehttp://www.elsevier.com/about/open-access/open-access-policies/article-posting-policy
dcterms.rightsHolderElsevier B.V.
unesp.author.orcid0000-0001-8062-7791[7]

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