Interaction mechanism of poly (o-ethoxyaniline) and collagen blends

dc.contributor.authorPiza, M. A.
dc.contributor.authorConstantino, CJL
dc.contributor.authorVenancio, E. C.
dc.contributor.authorMattoso, LHC
dc.contributor.institutionEmpresa Brasileira de Pesquisa Agropecuária (EMBRAPA)
dc.contributor.institutionUniversidade Estadual Paulista (Unesp)
dc.date.accessioned2014-05-20T13:22:53Z
dc.date.available2014-05-20T13:22:53Z
dc.date.issued2003-09-01
dc.description.abstractBlend films of poly (o-ethoxyaniline) (POEA) and collagen were fabricated by casting under optimized conditions and characterized by Raman scattering and UV-vis absorption spectroscopies. The UV-vis spectra showed that the addition of collagen in the aqueous solution of POEA promotes a dedoping of the POEA. This effect was also observed for the blend films as supported by Raman scattering and a mechanism for the chemical interaction between POEA-collagen is proposed. The influences of different percentage of collagen as well as the pH of stock solutions during the fabrication process of the blend films were also investigated. It was found that the preparation method plays an important role in the flexibility and freestanding properties of the films. Complementary, the surface morphology was studied by atomic force microscopy and the conductivity by dc measurements. (C) 2003 Elsevier Ltd. All rights reserved.en
dc.description.affiliationEMBRAPA, CNPDIA, Embrapa Instrument Agropecuaria, BR-13560970 Sao Carlos, SP, Brazil
dc.description.affiliationUNESP, FCT, Dept Fis Quim & Biol, BR-19060900 Presdiente Prudente, SP, Brazil
dc.description.affiliationUnespUNESP, FCT, Dept Fis Quim & Biol, BR-19060900 Presdiente Prudente, SP, Brazil
dc.format.extent5663-5670
dc.identifierhttp://dx.doi.org/10.1016/S0032-3861(03)00612-8
dc.identifier.citationPolymer. Oxford: Elsevier B.V., v. 44, n. 19, p. 5663-5670, 2003.
dc.identifier.doi10.1016/S0032-3861(03)00612-8
dc.identifier.issn0032-3861
dc.identifier.urihttp://hdl.handle.net/11449/6791
dc.identifier.wosWOS:000185182500023
dc.language.isoeng
dc.publisherElsevier B.V.
dc.relation.ispartofPolymer
dc.relation.ispartofjcr3.483
dc.relation.ispartofsjr1,097
dc.rights.accessRightsAcesso restrito
dc.sourceWeb of Science
dc.subjectconducting polymerpt
dc.subjectcollagenpt
dc.subjectblendpt
dc.titleInteraction mechanism of poly (o-ethoxyaniline) and collagen blendsen
dc.typeArtigo
dcterms.licensehttp://www.elsevier.com/about/open-access/open-access-policies/article-posting-policy
dcterms.rightsHolderElsevier B.V.
unesp.author.orcid0000-0001-7586-1014[4]
unesp.campusUniversidade Estadual Paulista (Unesp), Faculdade de Ciências e Tecnologia, Presidente Prudentept
unesp.departmentFísica, Química e Biologia - FCTpt

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