Effect of Isomerization and Copolymerization of Itaconic Anhydride During the Synthesis of Renewable Monomers Using Vegetable Oils

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dc.contributor.authorGaglieri, Caroline [UNESP]
dc.contributor.authorAlarcon, Rafael T.
dc.contributor.authorMoura, Aniele de [UNESP]
dc.contributor.authorMagri, Raquel [UNESP]
dc.contributor.authorRinaldo, Daniel [UNESP]
dc.contributor.authorBannach, Gilbert [UNESP]
dc.contributor.institutionUniversidade Estadual Paulista (UNESP)
dc.contributor.institutionUniversidade de São Paulo (USP)
dc.date.accessioned2023-07-29T11:56:23Z
dc.date.available2023-07-29T11:56:23Z
dc.date.issued2022-10-27
dc.description.abstractVegetable oils are alternatives to producing renewable monomers since they are biomass. It is possible to react them with anhydrides by heating to provide monomers with high reactivity. However, after the reaction of grape seed oil with itaconic anhydride, it was observed the occurrence of parallel reactions that had not been observed when the same oil was reacted with maleic anhydride. Some articles in the literature have reported that temperature and bases can isomerize itaconic anhydride into citraconic anhydride, which is more stable at room temperature. However, they have not focused on completely understanding how this phenomenon occurred nor studied it in processes that involve microwave irradiation. Therefore, this paper presents a complete characterization and investigation about the thermal behavior of itaconic anhydride and how it can affect the monomer synthesis performed under heating.en
dc.description.affiliationUniv Estadual Paulista Julio de Mesquita Filho Une, Fac Ciencias, Dept Quim, Lab Mat Polimer, BR-17033260 Bauru, SP, Brazil
dc.description.affiliationUniv Sao Paulo, Lab Anal Term Eletroanalit & Quim Solucoes LATEQS, Inst Quim Sao Carlos IQSC, BR-13566590 Sao Carlos, SP, Brazil
dc.description.affiliationUniv Estadual Paulista Julio de Mesquita Filho Une, Inst Estudos Avancados Mar IEAMAR, BR-11350011 Sao Vicente, SP, Brazil
dc.description.affiliationUnespUniv Estadual Paulista Julio de Mesquita Filho Une, Fac Ciencias, Dept Quim, Lab Mat Polimer, BR-17033260 Bauru, SP, Brazil
dc.description.affiliationUnespUniv Estadual Paulista Julio de Mesquita Filho Une, Inst Estudos Avancados Mar IEAMAR, BR-11350011 Sao Vicente, SP, Brazil
dc.description.sponsorshipCoordenação de Aperfeiçoamento de Pessoa de Nível Superior (CAPES)
dc.description.sponsorshipFundação de Amparo de Pesquisa do Estado de São Paulo (FAPESP)
dc.description.sponsorshipConselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)
dc.description.sponsorshipIdCAPES: 024/2012
dc.description.sponsorshipIdCAPES: 011/2009
dc.description.sponsorshipIdFAPESP: 2021/02152-9
dc.description.sponsorshipIdFAPESP: 2021/14879-0
dc.description.sponsorshipIdCNPq: 150233/2022-1
dc.description.sponsorshipIdCNPq: 303247/2021-5
dc.format.extent14
dc.identifierhttp://dx.doi.org/10.21577/0103-5053.20220134
dc.identifier.citationJournal of the Brazilian Chemical Society. Sao Paulo: Soc Brasileira Quimica, 14 p., 2022.
dc.identifier.doi10.21577/0103-5053.20220134
dc.identifier.issn0103-5053
dc.identifier.urihttp://hdl.handle.net/11449/245488
dc.identifier.wosWOS:000879559200001
dc.language.isoeng
dc.publisherSoc Brasileira Quimica
dc.relation.ispartofJournal Of The Brazilian Chemical Society
dc.sourceWeb of Science
dc.subjectbiomass
dc.subjectcitraconic anhydride
dc.subjectitaconic anhydride
dc.subjectgrape seed oil
dc.subjectthermal copolymerization
dc.subjectsolvent effect
dc.titleEffect of Isomerization and Copolymerization of Itaconic Anhydride During the Synthesis of Renewable Monomers Using Vegetable Oilsen
dc.typeArtigo
dcterms.rightsHolderSoc Brasileira Quimica
unesp.author.orcid0000-0001-9612-6887[1]
unesp.author.orcid0000-0003-3180-3490[4]
unesp.author.orcid0000-0002-8790-5069[6]
unesp.departmentQuímica - FCpt

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Bauru - FC - Faculdade de Ciências
Artigos - Ciências Biológicas - São Vicente